The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+)
文献类型：期刊论文
| 作者 | Sun, B; Yang, JZ; Song, PS; Deng, M; Gao, YY |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 1999 |
| 卷号 | 57期号:9页码:992-996 |
| 关键词 | Borate Ion Pair Association Constant Emf Pitzer Theory Association Entropy |
| 文献子类 | Article |
| 英文摘要 | Emfs for the cell without liquid junction:Pt, H-2(101.325kPa) \ Li2B4O7 (m(1)), CaCl2 (m(2)) \ AgCl - Ag are reported at five temperatures from 278.15 to 318.15 It. The standard association constant of ionic pair [CaB(OH)(4)](+), K-d is determined by fitting to the cell results. The dependence of pK(d) on temperature T is expressed by an empirical equation: pk(d) = 0.6857 - 359.72/ T - 4.632 x 10(-3) T. The other thermodynamic quantities of the association process are also calculated. The results show that the driving force for the ion association reaction is association entropy. |
| WOS关键词 | CHLORIDE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000082978300008 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6023]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 2.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, B,Yang, JZ,Song, PS,et al. The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+)[J]. ACTA CHIMICA SINICA,1999,57(9):992-996. |
| APA | Sun, B,Yang, JZ,Song, PS,Deng, M,&Gao, YY.(1999).The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+).ACTA CHIMICA SINICA,57(9),992-996. |
| MLA | Sun, B,et al."The thermodynamics of aqueous borate solutions 4. The standard association constant of ion pair [CaB(OH)(4)](+)".ACTA CHIMICA SINICA 57.9(1999):992-996. |
入库方式： OAI收割
来源：青海盐湖研究所
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