中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes

文献类型:期刊论文

作者Li, YT; Yan, CW; Wang, HD
刊名POLISH JOURNAL OF CHEMISTRY
出版日期2000-12-01
卷号74期号:12页码:1655-1663
关键词Magnetism Copper(Ii) Lanthanide(Iii) Heterobinuclear Complexes Oxamido Bridging
文献子类Article
英文摘要Tell new mu -oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes described by the overall formula Cu(Br(4)Obbz)Ln(phen)(2)NO3 (Ln = Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er), where Br(4)obbz denotes the oxamido-N,N'-bis(3,5-dibromobenzoato) and phen represents 1,10-phenanthroline, have been synthesized and characterized by the elemental analyses, magnetic moments (at room temperature), molar conductivity measurements and spectroscopic (IR, UV, ESR) studies. The temperature dependence of the magnetic susceptibility of Cu(Br(4)obbz)Gd(phen)(2)NO3 complex was measured over the range 4.2-300 K. The least-squares fit of the experimental susceptibilities based on the spin Hamiltonian operator, (H) over cap=-2J (S) over cap (1).(S) over cap (2), yielded J= +3.7 cm(-1). This result indicates the presence of a weak ferromagnetic spin-exchange interaction between Gd(III) and Cu(II) ions.
WOS关键词CRYSTAL-STRUCTURE ; LANTHANIDE ; LIGAND
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000165659700001
源URL[http://ir.isl.ac.cn/handle/363002/6032]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Qufu Normal Univ, Dept Chem, Shandong 273165, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Li, YT,Yan, CW,Wang, HD. Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes[J]. POLISH JOURNAL OF CHEMISTRY,2000,74(12):1655-1663.
APA Li, YT,Yan, CW,&Wang, HD.(2000).Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes.POLISH JOURNAL OF CHEMISTRY,74(12),1655-1663.
MLA Li, YT,et al."Synthesis, characterization and magnetic study of mu-oxamido-bridged copper(II)-lanthanide(III) heterobinuclear complexes".POLISH JOURNAL OF CHEMISTRY 74.12(2000):1655-1663.

入库方式: OAI收割

来源:青海盐湖研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。