Thermodynamics of ionic association 1 - The standard association constant of the ion pair Li+B(OH)(4)(-)
文献类型：期刊论文
| 作者 | Yang, JZ; Sun, B; Song, PS |
| 刊名 | THERMOCHIMICA ACTA
 |
| 出版日期 | 2000-07-03 |
| 卷号 | 352页码:69-74 |
| 关键词 | Thermodynamics Ionic Association Pitzer's Equation Borate Activity Coefficient |
| 文献子类 | Article |
| 英文摘要 | Values of cmf for the cell without liquid junction Pt, H-2 (101.325 kPa)\ Li2B4O7 (m(1)), LiCl (m(2))\ AgCl-Ag are reported at five temperatures from 278.15 to 318.15 K. The standard association constant of ionic pair Li+B(OH)(4)(-), K-a, is determined by a fitting with the cell results. The dependence of pK(a) on temperature Tis expressed in empirical equation. pK(a)=-131.6K/T-0.08996-1.856x10(-3)T/K. The other thermodynamic quantities of the association process are calculated and show that there truly exists ion pair Li+B(OH)(4)(-) and the driving force for the ion association reaction is association entropy. (C) 2000 Elsevier Science B.V. All rights reserved. |
| WOS关键词 | AQUEOUS BORATE SOLUTIONS ; BORIC-ACID ; CHLORIDE ; SYSTEM |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000087272900012 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6038]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, JZ,Sun, B,Song, PS. Thermodynamics of ionic association 1 - The standard association constant of the ion pair Li+B(OH)(4)(-)[J]. THERMOCHIMICA ACTA,2000,352:69-74. |
| APA | Yang, JZ,Sun, B,&Song, PS.(2000).Thermodynamics of ionic association 1 - The standard association constant of the ion pair Li+B(OH)(4)(-).THERMOCHIMICA ACTA,352,69-74. |
| MLA | Yang, JZ,et al."Thermodynamics of ionic association 1 - The standard association constant of the ion pair Li+B(OH)(4)(-)".THERMOCHIMICA ACTA 352(2000):69-74. |
入库方式： OAI收割
来源：青海盐湖研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。