Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution
文献类型:期刊论文
作者 | Ma, YT; Xia, SP; Gao, SY |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 2001-11-01 |
卷号 | 17期号:11页码:1021-1026 |
关键词 | Borate Supersaturated Solution Crystallization Kinetics Macallisterite Hungchaoite |
文献子类 | Article |
英文摘要 | The supersaturated solution of MgO . 3B(2)O(3)-18% MgSO4-H2O was prepared and kept in a thermostat of (20 +/- 0.1) degreesC. The crystallization processes of Mg-borates from the solution have been studied by the kinetic method. With the aid of simplex optinum method and digital integration as well as runge-kutta digital solution of differential equation system, the experimental data have been fitted and the kinetic parameters have been evaluated by computer. The crystallization kinetic equation has been given. There are two solid phases, Macallisterite (MgO . 3B(2)O(3) . 7.5H(2)O) was firstly crystallized out from the solution and then hungchaoite (MgO . 2B(2)O(3) . 9H(2)O). The solid phases were identified by IR-spectra, X-ray powder diffraction and TG-DSC thermal analysis. |
WOS关键词 | SALT LAKE BRINE ; CHEMISTRY |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000172252600012 |
源URL | [http://ir.isl.ac.cn/handle/363002/6042] ![]() |
专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China 2.Shaanxi Normal Univ, Inst Appl Chem, Xian 710062, Peoples R China 3.Qinghai Univ, Coll Chem Engn, Xining 810016, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, YT,Xia, SP,Gao, SY. Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution[J]. ACTA PHYSICO-CHIMICA SINICA,2001,17(11):1021-1026. |
APA | Ma, YT,Xia, SP,&Gao, SY.(2001).Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution.ACTA PHYSICO-CHIMICA SINICA,17(11),1021-1026. |
MLA | Ma, YT,et al."Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution".ACTA PHYSICO-CHIMICA SINICA 17.11(2001):1021-1026. |
入库方式: OAI收割
来源:青海盐湖研究所
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