中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution

文献类型:期刊论文

作者Ma, YT; Xia, SP; Gao, SY
刊名ACTA PHYSICO-CHIMICA SINICA
出版日期2001-11-01
卷号17期号:11页码:1021-1026
关键词Borate Supersaturated Solution Crystallization Kinetics Macallisterite Hungchaoite
文献子类Article
英文摘要The supersaturated solution of MgO . 3B(2)O(3)-18% MgSO4-H2O was prepared and kept in a thermostat of (20 +/- 0.1) degreesC. The crystallization processes of Mg-borates from the solution have been studied by the kinetic method. With the aid of simplex optinum method and digital integration as well as runge-kutta digital solution of differential equation system, the experimental data have been fitted and the kinetic parameters have been evaluated by computer. The crystallization kinetic equation has been given. There are two solid phases, Macallisterite (MgO . 3B(2)O(3) . 7.5H(2)O) was firstly crystallized out from the solution and then hungchaoite (MgO . 2B(2)O(3) . 9H(2)O). The solid phases were identified by IR-spectra, X-ray powder diffraction and TG-DSC thermal analysis.
WOS关键词SALT LAKE BRINE ; CHEMISTRY
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000172252600012
源URL[http://ir.isl.ac.cn/handle/363002/6042]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
2.Shaanxi Normal Univ, Inst Appl Chem, Xian 710062, Peoples R China
3.Qinghai Univ, Coll Chem Engn, Xining 810016, Peoples R China
推荐引用方式
GB/T 7714
Ma, YT,Xia, SP,Gao, SY. Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution[J]. ACTA PHYSICO-CHIMICA SINICA,2001,17(11):1021-1026.
APA Ma, YT,Xia, SP,&Gao, SY.(2001).Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution.ACTA PHYSICO-CHIMICA SINICA,17(11),1021-1026.
MLA Ma, YT,et al."Crystallization kinetics of Mg-borates from MgO center dot 3B(2)O(3)-18%MgSO4-H2O supersaturated solution".ACTA PHYSICO-CHIMICA SINICA 17.11(2001):1021-1026.

入库方式: OAI收割

来源:青海盐湖研究所

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