Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K
文献类型：期刊论文
| 作者 | Jiang, YC; Gao, SY; Xia, SP; Wang, JJ; Zhuo, KL; Hu, MC |
| 刊名 | JOURNAL OF CHEMICAL THERMODYNAMICS
 |
| 出版日期 | 2002-12-01 |
| 卷号 | 34期号:12页码:1959-1973 |
| 关键词 | Thermodynamic Parameter Cscl Monosaccharide Ion Selective Electrode |
| 文献子类 | Article |
| 英文摘要 | A non-liquid-junction electrochemical cell composed of a potassium ion selective electrode(K-ISE) against a chloride ion selective electrode (Cl-ISE) as a reference electrode was employed to study the thermodynamic parameters of weak interactions between aqueous cesium chloride and the monosaccharides (D-glucose, D-galactose, D-xylose, and D-arabinose) at T = 298.15 K. Activity coefficients for this system obtained from electromotive force measurements indicate that they have a close relationship with the stereostructure of the saccharide. The Gibbs free energy pair interaction parameters and salting constants were also evaluated; these can characterize the interaction between the saccharides and CsCl in water. The results were interpreted on the basis of a model of structural and electrostatic interaction and the hydration effect of the hydroxyl ion of these saccharides. (C) 2002 Elsevier Science Ltd. All rights reserved. |
| WOS关键词 | TRIVALENT LANTHANIDE CATIONS ; 278.15-318.15 K ; ACTIVITY-COEFFICIENTS ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; NACL ; HCL ; SYSTEMS ; SUGARS ; COMPLEXATION |
| WOS研究方向 | Thermodynamics ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000179963900004 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6070]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China 2.Henan Normal Univ, Sch Chem & Environm Sci, Henan 453002, Peoples R China 3.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi 710062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, YC,Gao, SY,Xia, SP,et al. Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2002,34(12):1959-1973. |
| APA | Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2002).Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K.JOURNAL OF CHEMICAL THERMODYNAMICS,34(12),1959-1973. |
| MLA | Jiang, YC,et al."Thermodynamic parameters of the interaction of CsCl with monosaccharide (D-glucose, D-galactose, D-xylose, and D-arabinose) in water at T=298.15K".JOURNAL OF CHEMICAL THERMODYNAMICS 34.12(2002):1959-1973. |
入库方式： OAI收割
来源：青海盐湖研究所
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