A comparison of loading reagent for boron isotopic measurement by negative thermal ionization mass spectrometry
文献类型:期刊论文
作者 | Liu, WG; Peng, ZC; Xiao, YK; Zhang, ZF |
刊名 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
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出版日期 | 2002-03-01 |
卷号 | 30期号:3页码:372-375 |
关键词 | Boron Isotopes Negative Thermal Ionization Mass Spectrometry Loading Agents |
文献子类 | Article |
英文摘要 | The isobaric (CNO- ions) interference involved in the loading reagents has not been noted for boron isotopic measurement by nagetive thermal ionization mass spectrometry (NTIMS). A comparison experiment of different loading reagents was investigated. The result revealed that high isobaric interference ion (CNO-) for boron isotopic measurement was observed in the boron-free seawater and the nitrate. Further, the CNO- was not only from the organic material, but also from nitrate in loading reagent in NTIMS. The isobaric interference in loading reagents may be a reason resulting to result in low boron isotopic ratios by NTIMS. So monitoring the mass 43 ion intensity and 43/42 ratio of blank are necessary for the boron isotopic measurement by NTIMS. The mixed solution of the MgCl2 and NaOH is a suitable loading reagent for boron isotopic measurement by NTIMS. |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000174719800032 |
源URL | [http://ir.isl.ac.cn/handle/363002/6073] ![]() |
专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Chinese Acad Sci, IEE, Key Lab Loess & Quaternary Geol, Xian 710075, Peoples R China 2.Univ Sci & Technol China, Dept Earth & Space Sci, Anhua 230026, Peoples R China 3.Acad Sinica, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, WG,Peng, ZC,Xiao, YK,et al. A comparison of loading reagent for boron isotopic measurement by negative thermal ionization mass spectrometry[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2002,30(3):372-375. |
APA | Liu, WG,Peng, ZC,Xiao, YK,&Zhang, ZF.(2002).A comparison of loading reagent for boron isotopic measurement by negative thermal ionization mass spectrometry.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,30(3),372-375. |
MLA | Liu, WG,et al."A comparison of loading reagent for boron isotopic measurement by negative thermal ionization mass spectrometry".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 30.3(2002):372-375. |
入库方式: OAI收割
来源:青海盐湖研究所
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