The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K
文献类型：期刊论文
| 作者 | Jiang, YC; Gao, SY; Xia, SP; Hu, MC; Wang, JJ; Lu, Y; Zhuo, KL |
| 刊名 | THERMOCHIMICA ACTA
 |
| 出版日期 | 2003-04-17 |
| 卷号 | 400期号:1-2页码:37-42 |
| 关键词 | Cesium Chloride Saccharides Enthalpy And Entropy Interaction Parameters |
| 文献子类 | Article |
| 英文摘要 | The transfer enthalpies have been measured for cesium chloride from pure water to aqueous saccharides (D-glucose, D-fructose and sucrose) solutions at 298.15 K. The McMillan-Mayer theory was employed to relate the excess thermodynamic function with a series of interaction parameters of solutes to obtain the enthalpy pair interaction parameters of cesium chloride with saccharides in water. Entropy interaction parameters can be evaluated through the enthalpy interaction parameters and the Gibbs free energy parameters. These parameters are discussed in detail to provide some information for the interaction of solute-solute and solute-solvent in CsCl-saccharide-water ternary system, and to investigate the influence of the size of metal ions and the number of hydroxyl in saccharides on these parameters. (C) 2002 Elsevier Science B.V. All rights reserved. |
| WOS关键词 | HEAT-CAPACITIES ; VOLUMES ; HALIDES ; BINDING ; UREA |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000182494100004 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6095]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xian 710043, Shaanxi, Peoples R China 3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, YC,Gao, SY,Xia, SP,et al. The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K[J]. THERMOCHIMICA ACTA,2003,400(1-2):37-42. |
| APA | Jiang, YC.,Gao, SY.,Xia, SP.,Hu, MC.,Wang, JJ.,...&Zhuo, KL.(2003).The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K.THERMOCHIMICA ACTA,400(1-2),37-42. |
| MLA | Jiang, YC,et al."The enthalpy and entropy interaction parameters of cesium chloride with saccharides (D-glucose, D-fructose and sucrose) in water at 298.15 K".THERMOCHIMICA ACTA 400.1-2(2003):37-42. |
入库方式： OAI收割
来源：青海盐湖研究所
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