Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K
文献类型：期刊论文
| 作者 | Jiang, YC; Gao, SY; Xia, SP; Wang, JJ; Zhuo, KL; Hu, MC |
| 刊名 | JOURNAL OF THE CHINESE CHEMICAL SOCIETY
 |
| 出版日期 | 2003-10-01 |
| 卷号 | 50期号:5页码:947-952 |
| 关键词 | Density Apparent Molar Volume Standard Transfer Volume Volumetric Interaction Parameter Cscl Saccharide |
| 文献子类 | Article |
| 英文摘要 | Densities have been measured for the CsCl-saccharide (D-glucose, D-fructose)-water systems at 298.15 K. These data were used to calculate the apparent molar volume of CsCl ( V-Phi,V-E) and the saccharides (V-Phi,V-S), and the infinite dilution apparent molar volume V-Phi,E(0) and V-Phi,S(0) in the studied solutions. In addition, the standard transfer volume Delta(t)V(phi,E)(0) of CsCl from water to aqueous saccharides solutions, and Delta(t)V(phi,S)(0) of saccharides from water to CsCl solutions have been evaluated and discussed using the structural interaction model. The volumetric interaction parameters for CsCl with saccharide in water were obtained and analyzed by the group additivity principle and the stereochemistry of the saccharide molecules. |
| WOS关键词 | APPARENT MOLAR VOLUMES ; AQUEOUS-SOLUTIONS ; HEAT-CAPACITIES ; STEREOCHEMICAL ASPECTS ; EXCESS-ENTHALPIES ; WATER ; HYDRATION ; SUGARS ; MONOSACCHARIDES ; THERMODYNAMICS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000186578700002 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6097]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Shaanxi, Peoples R China 3.Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453002, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, YC,Gao, SY,Xia, SP,et al. Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY,2003,50(5):947-952. |
| APA | Jiang, YC,Gao, SY,Xia, SP,Wang, JJ,Zhuo, KL,&Hu, MC.(2003).Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K.JOURNAL OF THE CHINESE CHEMICAL SOCIETY,50(5),947-952. |
| MLA | Jiang, YC,et al."Volumetric properties and volumetric interaction parameters of the CsCl-saccharides (D-glucose, D-fructose)-water solutions at 298.15 K".JOURNAL OF THE CHINESE CHEMICAL SOCIETY 50.5(2003):947-952. |
入库方式： OAI收割
来源：青海盐湖研究所
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