Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K
文献类型：期刊论文
| 作者 | Jiang, YC; Wang, JJ; Zhuo, KL; Gao, SY; Xia, SP; Hu, MC |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2003-10-10 |
| 卷号 | 24期号:10页码:1842-1846 |
| 关键词 | Cscl Glucose Fructose Sucrose Weak Interaction Thermodynamic Parameters |
| 文献子类 | Article |
| 英文摘要 | Electrochemical cells with a potassium ion selectivity electrode (Na-ISE) as a measuring electrode versus a chloride ion selectivity electrode as a reference electrode (Cl-ISE) were used to investigate the interaction of solute-solute and solute-solvent in the CsCl-saccharide(D-glucose, D-fructose and sucrose)-, water ternary system at 298.15 K. The activity coefficients of CsCl in saccharides aqueous solutions can be determined through the measurements of electromotive force, and the activity coefficients of saccharides in CsCl aqueous solutions can be evaluated in terms of the Scatchard theory. The McMillan-Mayer theory is employed to relate the excess thermodynamic function with a series of interaction parameters of solute in water so as to obtain the pair Gibbs free energy interaction parameters and salting constant. These parameters have been analyzed by using the model of structural interaction, the effect of hydration of hydroxyl of saccharide and the theory of dispersion energy and the stereostructure of saccharides, which indicates that the interactions of these saccharides with CsCl are controlled mostly by the structure and conformation of their molecules in water. |
| WOS关键词 | TRIVALENT LANTHANIDE CATIONS ; ACTIVITY-COEFFICIENTS ; AQUEOUS-SOLUTIONS ; SYSTEMS ; NACL ; 25-DEGREES-C ; COMPLEXATION ; ALDITOLS ; MIXTURES ; BINDING |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000186135000029 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6101]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Peoples R China 2.Henan Normal Univ, Xinxiang 4530023, Peoples R China 3.Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, YC,Wang, JJ,Zhuo, KL,et al. Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,24(10):1842-1846. |
| APA | Jiang, YC,Wang, JJ,Zhuo, KL,Gao, SY,Xia, SP,&Hu, MC.(2003).Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,24(10),1842-1846. |
| MLA | Jiang, YC,et al."Thermodynamic parameters of interaction of CsCl with D-glucose, D-fructose and D-sucrose in water at 298.15 K".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 24.10(2003):1842-1846. |
入库方式： OAI收割
来源：青海盐湖研究所
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