Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material
文献类型：期刊论文
| 作者 | Zhou, Y; Jian, YZ; Yan, JM; Yang, JX; Wang, ZC; Jing, Y |
| 刊名 | CHINESE JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2003-12-01 |
| 卷号 | 19期号:12页码:1307-1310 |
| 关键词 | Li2.6co0.4n Litium Ion intercalatIon Free Energy Li-ion Electrochemical Diffusion Coefficient Crystal Structure |
| 文献子类 | Article |
| 英文摘要 | Under the circumstance of NH3, the new anode material Li2.6Co0.4N for lithium ion battery was prepared by using Li3N and Co powders as raw materials. The structure and the lithium intercalation properties were investigated by I means of XRD and coulombic titration. The results show that Li2.6Co0.4N has a hexagonal structure with the unit cell parameters: a = 0. 500 nm, c = 0. 387 nm; Its capacity is 829 mAh . g(-1). The maximum intercalation of Li+ is 1.7215. The intercalation free energy (DeltaG(in)) of Li+ is -223.98 kj . mol(-1). The value of Li-ion electrochemical diffusion coefficient (D) is 4.6 x 10(-10) similar to 2.65 x 10(-9) cm(2) . s(-1). And also, a series of other thermodynamic and kinetic parameters were gained. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000187026200007 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6109]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | Chinese Acad Sci, Inst Salt Lake, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Y,Jian, YZ,Yan, JM,et al. Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2003,19(12):1307-1310. |
| APA | Zhou, Y,Jian, YZ,Yan, JM,Yang, JX,Wang, ZC,&Jing, Y.(2003).Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material.CHINESE JOURNAL OF INORGANIC CHEMISTRY,19(12),1307-1310. |
| MLA | Zhou, Y,et al."Preparation and studies on the thermodynamic and kinetic properties of lithium intercalation of Li2.6C0.4N material".CHINESE JOURNAL OF INORGANIC CHEMISTRY 19.12(2003):1307-1310. |
入库方式： OAI收割
来源：青海盐湖研究所
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