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A new theory for ionic liquids - the Interstice Model Part 1. The density and surface tension of ionic liquid EMISE
文献类型：期刊论文
| 作者 | Yang, JZ; Lu, XM; Gui, JS; Xu, WG |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2004 |
| 卷号 | 6期号:11页码:541-543 |
| 文献子类 | Article |
| 英文摘要 | This paper reports measurements of the surface tension of ionic liquid EMISE (1-ethyl-3-methylimidazolium ethyl sulfate) using the forced bubble method at 278.15 to 323.15 K and densities of EMISE using a Westphal balance at 278.15 to 338.15 K. At the same time, a new theoretical model, the interstice model, is put forward. Applying the model, an expression of the average volume of the interstices, nu, was obtained. The calculated volume fraction of the total interstices is 0.12 for ionic liquid EMISE and is in good agreement with that of the majority of materials which exhibit a 10similar to15% volume expansion in transition from the solid to liquid state. The value of the thermal expansion coefficient calculated from the model is 5.24x10(-4) K-1 and is in good agreement with the experimental value 5.37x10(-4) K-1 at 298.15 K. |
| WOS关键词 | THERMODYNAMICS ; CHLORIDE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000225166100002 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6127]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Shenyang Normal Univ, Dept Chem, Shenyang 110032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, JZ,Lu, XM,Gui, JS,et al. A new theory for ionic liquids - the Interstice Model Part 1. The density and surface tension of ionic liquid EMISE[J]. GREEN CHEMISTRY,2004,6(11):541-543. |
| APA | Yang, JZ,Lu, XM,Gui, JS,&Xu, WG.(2004).A new theory for ionic liquids - the Interstice Model Part 1. The density and surface tension of ionic liquid EMISE.GREEN CHEMISTRY,6(11),541-543. |
| MLA | Yang, JZ,et al."A new theory for ionic liquids - the Interstice Model Part 1. The density and surface tension of ionic liquid EMISE".GREEN CHEMISTRY 6.11(2004):541-543. |
入库方式： OAI收割
来源：青海盐湖研究所
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