Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K
文献类型：期刊论文
| 作者 | Jiang, YC; Hu, MC; Mu, PF; Wang, JJ; Zhuo, KL; Xia, SP |
| 刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| 出版日期 | 2004-09-01 |
| 卷号 | 49期号:5页码:1418-1421 |
| 文献子类 | Article |
| 英文摘要 | Electromotive forces of cells without liquid junctions K-ISE \ CsCl(m(E)) \ ISE-Cl and K-ISE \ CsCl(m(E)), glucose(m(S)) \ ISE-Cl have been measured at 5 K intervals from T = 278.15 to 313.15 K, where m(E) = (0.001 to 0.1) mol kg(-1) and m(S) = (0.01 to 3.0) mol kg(-1). The activity coefficients of CsCl in glucose + water solutions can be obtained from these electromotive force data; in the meantime, the interaction parameters of the CsCl + glucose pair in water, g(EN), h(EN), s(EN), and c(p,EN), can be evaluated. We show that g(EN) > 0, h(EN) > 0, s(EN) > 0, and c(p,EN) < 0 at all four temperatures (except for h(EN) and s(EN) at T = 313.15 K), and the values of g(EN), s(EN), and c(p,EN) vary slightly with temperature, whereas the values of h(EN) is very sensitive to the temperatures used. These thermodynamic parameters were discussed in terms of a model of the structural interaction and electrostatic interaction and were analyzed by the group additivity principle. |
| WOS关键词 | AQUEOUS-SOLUTIONS ; MOLAR VOLUMES ; FREE-ENERGIES ; AMINO-ACIDS ; D-ARABINOSE ; D-GALACTOSE ; D-XYLOSE ; ENTHALPIES ; PARAMETERS ; ASSOCIATION |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000223833100050 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6132]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 作者单位 | 1.Shaanxi Normal Univ, Sch Chem & Mat Sci, Shaanxi 710062, Peoples R China 2.Henan Normal Univ, Coll Chem & Environm Sci, Henan 453002, Peoples R China 3.Chinese Acad Sci, Inst Salt Lake, Xian 710043, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, YC,Hu, MC,Mu, PF,et al. Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2004,49(5):1418-1421. |
| APA | Jiang, YC,Hu, MC,Mu, PF,Wang, JJ,Zhuo, KL,&Xia, SP.(2004).Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,49(5),1418-1421. |
| MLA | Jiang, YC,et al."Thermodynamics study of the interaction of CsCl with D-glucose in water from T=278.15 to 313.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 49.5(2004):1418-1421. |
入库方式： OAI收割
来源：青海盐湖研究所
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