Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone
文献类型：期刊论文
| 作者 | Zhao, Jing-Jing1; Pei, Hao1; Chen, Yan-Mei1,2; Lu, Ning1; Liu, Jin-Na1; Hu, Jin-Fa1; Liu, Wei1; Li, Wu2 ; Li, Yahong1
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| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
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| 出版日期 | 2015-06-01 |
| 卷号 | 641期号:7页码:1322-1328 |
| 关键词 | Hydroamination Titanium Ring-opening Polymerization E-caprolactone |
| 文献子类 | Article |
| 英文摘要 | The ligands 2-pyrazol-1-yl-1H-indole (HL1) and 2-1,2,4-triazol-1-yl-1H-indole (HL2) individually reacted with Ti(NMe2)(4) in tetrahydrofuran to form the corresponding complexes Ti(L1)(2)(NMe2)(2) (1) and Ti(L2)(2)(NMe2)(2) (2), respectively. The titanium complexes were fully characterized by NMR measurement and elemental analysis as well as the single-crystal X-ray diffraction of 1 and 2. Both 1 and 2 exhibit high activities towards intermolecular hydroamination of terminal alkynes with high selectivity, and they also efficiently promote the ring-opening polymerization of E-caprolactone. |
| WOS关键词 | INTRAMOLECULAR ALKENE HYDROAMINATION ; INTERMOLECULAR ALKYNE HYDROAMINATION ; N BOND FORMATION ; TITANIUM COMPLEXES ; C-N ; ALPHA,BETA-UNSATURATED IMINES ; ASYMMETRIC HYDROAMINATION ; AMIDATE COMPLEXES ; TERMINAL ALKYNES ; ZIRCONIUM |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000356722400023 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6146]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Jing-Jing,Pei, Hao,Chen, Yan-Mei,et al. Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2015,641(7):1322-1328. |
| APA | Zhao, Jing-Jing.,Pei, Hao.,Chen, Yan-Mei.,Lu, Ning.,Liu, Jin-Na.,...&Li, Yahong.(2015).Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,641(7),1322-1328. |
| MLA | Zhao, Jing-Jing,et al."Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of E-Caprolactone".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 641.7(2015):1322-1328. |
入库方式： OAI收割
来源：青海盐湖研究所
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