Cu-II and Cu-I Complexes of 1,1 '-(Pyridin-2-ylmethylene)-bis[3-(pyridin-2-yl)imidazo[1,5-a]pyridine]: in situ Generation of the Ligand via Acetic Acid-controlled Metal-ligand Reactions
文献类型：期刊论文
| 作者 | Zhang Hai-Feng1; Chen Yan-Mei1; Qin Ya-Ru1; Li Ya-Hong1; Li Wu2
|
| 刊名 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
 |
| 出版日期 | 2015-09-01 |
| 卷号 | 34期号:9页码:1417-1427 |
| 关键词 | Coordination Chemistry Imidazo[1 Cu-ii Complex 5-a]Pyridine |
| 文献子类 | Article |
| 英文摘要 | Reaction of 3-(pyridin-2-y1)-imidazo[1,5-a]pyridine (HPIP), CuCl2.2H(2)O and picolinaldehyde in the mixture of CH3COOH and EtOH under solvothermal conditions gave complexes [LCuCl][Cu2Cl3] (1) and [HLCuCl](2)[CuCl2](2)[CuCl3].2H(2)O (2) = 1X-(pyridin-2-yl-methylene)bis[3-(pyridin-2-yl)imidazo[1,5-a]pyridine]) simultaneously. The ligand L was generated via in situ metal-ligand reaction between HPIP and picolinaldehyde. When CuCl2.2H(2)O was replaced by CuCl, the 2:1:1 (HPIP:picolinaldehyde:CuCl) reaction afforded complex [Cu3L2Cl2][CuCl2].2H(2)O (3) and the analogous 2:1:3 reaction generated compound [Cu3L2] [CuCl2](3) (4). Complexes 1 and 2 are Cu-II/Cu-I mixed-valence compounds. Complexes 1 similar to 4 display four various structures. It is found that the formation of the L ligand is controlled by CH3COOH. This work reveals that the structures of complexes 1 similar to 4 could be rationally tuned via the inclusion of CH3COOH in the reaction systems, the proper selection of different starting materials and the dexterous adjustment of the ratio of the starting materials. |
| WOS关键词 | MAGNETIC-PROPERTIES ; COPPER-COMPLEXES ; IMIDAZOLES ; CHAIN |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000362142500016 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6162]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Hai-Feng,Chen Yan-Mei,Qin Ya-Ru,et al. Cu-II and Cu-I Complexes of 1,1 '-(Pyridin-2-ylmethylene)-bis[3-(pyridin-2-yl)imidazo[1,5-a]pyridine]: in situ Generation of the Ligand via Acetic Acid-controlled Metal-ligand Reactions[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2015,34(9):1417-1427. |
| APA | Zhang Hai-Feng,Chen Yan-Mei,Qin Ya-Ru,Li Ya-Hong,&Li Wu.(2015).Cu-II and Cu-I Complexes of 1,1 '-(Pyridin-2-ylmethylene)-bis[3-(pyridin-2-yl)imidazo[1,5-a]pyridine]: in situ Generation of the Ligand via Acetic Acid-controlled Metal-ligand Reactions.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,34(9),1417-1427. |
| MLA | Zhang Hai-Feng,et al."Cu-II and Cu-I Complexes of 1,1 '-(Pyridin-2-ylmethylene)-bis[3-(pyridin-2-yl)imidazo[1,5-a]pyridine]: in situ Generation of the Ligand via Acetic Acid-controlled Metal-ligand Reactions".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 34.9(2015):1417-1427. |
入库方式： OAI收割
来源：青海盐湖研究所
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