Assembly of a New Fluorescent Cd(II) Coordination Compound with a Versatile Multidentate N-Donor Building Block 3-(2-Pyridyl)-5-(3 '-pyridyl)-1,2,4-triazole
文献类型：期刊论文
| 作者 | Li Ting1; Meng Qing-Fen2; Li Bing1; Jin Xiao-Dong1; Gao Hui1; Chen Xiao-Yan1; Song Wei-Ming1; Liu Wan-Yi1 |
| 刊名 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
 |
| 出版日期 | 2015-10-01 |
| 卷号 | 34期号:10页码:1525-1532 |
| 关键词 | Benzoic Acid 2 Cadmium(Ii) Complex 3 '-hbpt Crystal Structure Luminescence |
| 文献子类 | Article |
| 英文摘要 | Assembly of Cd(II) nitrate with a new dipyridyltriazole building block 3-(2-pyridyl)-5-(3'-pyridyl)-1H-1,2,4-triazole (2,3'-Hbpt) and benzoic acid (Hba) yields a new coordination compound [Cd(2,3'-bpt(ba)(H2O)] which was characterized by single-crystal X-ray diffraction, elemental analysis, IR spectrum, TGA and XRPD analysis. Single-crystal X-ray diffraction analysis indicates that the complex belongs to triclinic system, space group P (1) over bar with a = 6.8972(6), b = 8.8182(7), c = 16.0484(1) angstrom, alpha = 75.6330(1), beta = 85.294(2), gamma = 69.3450(1)degrees, V = 884.76(13) angstrom(3), Z = 2, D-c = 1.778 g/cm(3), mu = 1.276 mm(-1), M-r = 473.76, F(000) = 472, the final R = 0.0380 and wR = 0.1054 with I> 2 sigma(I). The Cd(II) ion is coordinated by three N-terminal atoms from two 2,3'-Hbpt ligands as well as three O-terminal atoms from ba(-) and lattice water forming a distorted octahedral coordinated geometry. With the lattice water as hydrogen bond donor, the structure of the title complex is linked into a 2D layer-hole structure from the 0D motif. Theoretical calculation based on density functional theory (DFT) for the ligand is also employed to explicate the stability of different conformations. Moreover, the complex exhibits strong solid state fluorescent emission at room temperature which indicates that the title complex could be a good candidate for potential photoactive materials. |
| WOS关键词 | THERMAL-DECOMPOSITION ; AMMONIUM-PERCHLORATE ; CRYSTAL-STRUCTURES ; ENERGETIC COMPLEX ; PYRIDYL-TRIAZOLE ; ACID SYNTHESIS ; POLYMERS ; LIGAND ; ZINC(II) |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000364610700009 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6167]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 |
| 作者单位 | 1.Ningxia Univ, Dept Chem & Chem Engn, Yinchuan 750021, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Ting,Meng Qing-Fen,Li Bing,et al. Assembly of a New Fluorescent Cd(II) Coordination Compound with a Versatile Multidentate N-Donor Building Block 3-(2-Pyridyl)-5-(3 '-pyridyl)-1,2,4-triazole[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2015,34(10):1525-1532. |
| APA | Li Ting.,Meng Qing-Fen.,Li Bing.,Jin Xiao-Dong.,Gao Hui.,...&Liu Wan-Yi.(2015).Assembly of a New Fluorescent Cd(II) Coordination Compound with a Versatile Multidentate N-Donor Building Block 3-(2-Pyridyl)-5-(3 '-pyridyl)-1,2,4-triazole.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,34(10),1525-1532. |
| MLA | Li Ting,et al."Assembly of a New Fluorescent Cd(II) Coordination Compound with a Versatile Multidentate N-Donor Building Block 3-(2-Pyridyl)-5-(3 '-pyridyl)-1,2,4-triazole".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 34.10(2015):1525-1532. |
入库方式： OAI收割
来源：青海盐湖研究所
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