Five Rare mu(4)-O-Centered Ln(6) Clusters with Single-Molecule Magnet Behavior for Dy-6
文献类型：期刊论文
| 作者 | Zhang, Haifeng1,2; Liu, Rui2; Zhang, Jin1; Li, Yahong1; Liu, Wei1; Dong, Yaping3
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| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2017-03-02 |
| 卷号 | 12期号:5页码:507-514 |
| 关键词 | Double Tetrahedron Isomorphism Lanthanides Magnetic Properties Polynuclear Complexes |
| 文献子类 | Article |
| 英文摘要 | Five hexanuclear lanthanide clusters of composition [Ln(6)(mu(4)-O)(2)(HCOO) L-2(4)(HL')(2)(dmf())2] [Ln=Dy (1), Er (2), Ho (3), Tb (4), Gd (5); H2L=2-{[2-(hydroxymethyl)phenylimino]methyl}-6-methoxyphenol; H3L'=3-{[2-(hydroxymethyl)phenylimino] methyl} benzene-1,2-diol; H3L' was derived in situ from the H2L ligand] were prepared under solvothermal conditions. The [Ln(6)] cores of 1-5 possess an unprecedented motif, namely, two tetrahedron Ln(4) units sharing an edge and two vertices. The six Ln(III) ions of 1-5 are connected through two mu(4)-O anions. Magnetic susceptibility studies reveal that complex 1 exhibits frequency dependence of the alternating current susceptibility typical of single-molecule magnets. Complex 1 possesses a relatively large energy barrier of 85 K among all of the reported Dy-6 single-molecule magnets. |
| WOS关键词 | EXCHANGE INTERACTION ; CRYSTAL-STRUCTURES ; SLOW RELAXATION ; ION LN ; HO-III ; CO-II ; NI-II ; COMPLEXES ; LIGAND ; MAGNETIZATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000398188200004 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6201]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Jining Univ, Dept Chem & Chem Engn, Qufu 273155, Peoples R China 3.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Haifeng,Liu, Rui,Zhang, Jin,et al. Five Rare mu(4)-O-Centered Ln(6) Clusters with Single-Molecule Magnet Behavior for Dy-6[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(5):507-514. |
| APA | Zhang, Haifeng,Liu, Rui,Zhang, Jin,Li, Yahong,Liu, Wei,&Dong, Yaping.(2017).Five Rare mu(4)-O-Centered Ln(6) Clusters with Single-Molecule Magnet Behavior for Dy-6.CHEMISTRY-AN ASIAN JOURNAL,12(5),507-514. |
| MLA | Zhang, Haifeng,et al."Five Rare mu(4)-O-Centered Ln(6) Clusters with Single-Molecule Magnet Behavior for Dy-6".CHEMISTRY-AN ASIAN JOURNAL 12.5(2017):507-514. |
入库方式： OAI收割
来源：青海盐湖研究所
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