中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Phase diagram of the NaCl-MgCl2-H2O system at 25-75A degrees C and its application for MgCl2 center dot 6H(2)O purification

文献类型:期刊论文

作者Han, Haijun1,2; Dong, Ouyang2; Li, Dongdong2; Zeng, Dewen1
刊名RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
出版日期2017-07-01
卷号91期号:7页码:1255-1259
关键词Phase Equilibria Purification Re-crystallization Magnesium Chloride Sodium Chloride
文献子类Article
英文摘要The co-saturation line for the solid phases NaCl(s) and MgCl2 center dot 6H(2)O((s)) in aqueous solution has been measured by a phase equilibrium at various temperatures. It was found that the Y (b) (Y (b) = w(NaCl)/(w(NaCl) + w(MgCl2))) value of the co-saturation line increase with increasing temperature. A new recrystallization approach has been suggested for the purification of MgCl2 center dot 6H(2)O((s)) containing quite amount of impurity NaCl, i.e., dissolving the crude sample at low temperatures, followed by evaporating and phase separating at high temperatures. Applying the proposed approach a crude MgCl2 center dot 6H(2)O((s)) sample can be purified to the level of Y (b) = 0.17% by only one crystallization process.
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000403501200015
源URL[http://ir.isl.ac.cn/handle/363002/6218]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
青海盐湖研究所_盐湖资源与化学实验室
作者单位1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Han, Haijun,Dong, Ouyang,Li, Dongdong,et al. Phase diagram of the NaCl-MgCl2-H2O system at 25-75A degrees C and its application for MgCl2 center dot 6H(2)O purification[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,2017,91(7):1255-1259.
APA Han, Haijun,Dong, Ouyang,Li, Dongdong,&Zeng, Dewen.(2017).Phase diagram of the NaCl-MgCl2-H2O system at 25-75A degrees C and its application for MgCl2 center dot 6H(2)O purification.RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,91(7),1255-1259.
MLA Han, Haijun,et al."Phase diagram of the NaCl-MgCl2-H2O system at 25-75A degrees C and its application for MgCl2 center dot 6H(2)O purification".RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A 91.7(2017):1255-1259.

入库方式: OAI收割

来源:青海盐湖研究所

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