Phase diagrams and thermochemical modeling of salt lake brine systems. I. LiCl+H2O system
文献类型：期刊论文
| 作者 | Li, Dongdong1,2 ; Zeng, Dewen1,3; Han, Haijun1; Guo, Lijiang1; Yin, Xia4; Yao, Yan1
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| 刊名 | CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
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| 出版日期 | 2015-12-01 |
| 卷号 | 51页码:1-12 |
| 关键词 | Phase Diagram Brine Modeling Pitzer-simonson-clegg Model Licl |
| 文献子类 | Article |
| 英文摘要 | Salt lake brine chemical engineering involves the study of the solid-liquid equilibria of more than one hundred water-salt systems and approximately 70 solid salts over a wide temperature range. Prediction of the crystallization behavior of these complex systems as a function of temperature can only be achieved using a thermodynamic model. However, no systematic simulation studies have been reported for the complex salt lake brine systems, especially those systems containing the highly soluble salt LiCl. To complete this task, we plan to carry out a series of work. As the first part of the series of work, the Pitzer-Simonson-Clegg (PSC) model is selected to represent the thermodynamic properties of the LiCl+H2O system in the temperature range of 190 K to nearly 400 K. In this model's framework, the temperature dependence of the thermodynamic functions (entropy, enthalpy and Gibbs energy) of the aqueous species and solid phases are determined using their heat capacities, which serves to keep their inner thermodynamics consistent and confers a strong extrapolation ability. The comprehensive thermodynamic properties, i.e., water activity, mean ionic activity coefficient, enthalpy of dilution and solution, heat capacity and solubility, are used to evaluate the model parameters. The proposed parameter regression strategy has proven successful for the LiCl+H2O system. The present work forms a solid foundation for the simulation of thermochemical properties of other complicated salt lake brine systems. (C) 2015 Elsevier Ltd. All rights reserved. |
| WOS关键词 | CHEMICAL-EQUILIBRIUM MODEL ; LITHIUM CHLORIDE-WATER ; THERMODYNAMIC PROPERTIES ; AQUEOUS-SOLUTIONS ; MINERAL SOLUBILITIES ; ACTIVITY-COEFFICIENTS ; NATURAL-WATERS ; OSMOTIC COEFFICIENTS ; HEAT-CAPACITIES ; VAPOR-PRESSURE |
| WOS研究方向 | Thermodynamics ; Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000366790500001 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6285]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 |
| 作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China 4.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Dongdong,Zeng, Dewen,Han, Haijun,et al. Phase diagrams and thermochemical modeling of salt lake brine systems. I. LiCl+H2O system[J]. CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY,2015,51:1-12. |
| APA | Li, Dongdong,Zeng, Dewen,Han, Haijun,Guo, Lijiang,Yin, Xia,&Yao, Yan.(2015).Phase diagrams and thermochemical modeling of salt lake brine systems. I. LiCl+H2O system.CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY,51,1-12. |
| MLA | Li, Dongdong,et al."Phase diagrams and thermochemical modeling of salt lake brine systems. I. LiCl+H2O system".CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY 51(2015):1-12. |
入库方式： OAI收割
来源：青海盐湖研究所
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