Two 3d-4f double helical chains including [Dy2M2](n) (M = Ni-II and Co-II) cores exhibiting slow magnetic relaxation
文献类型：期刊论文
| 作者 | She, Shixiong1; Li, Yahong1; Li, Wu2
|
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2016 |
| 卷号 | 45期号:26页码:10830-10835 |
| 文献子类 | Article |
| 英文摘要 | Two new 3d-4f heterometallic 1D chains of formulae {[Dy2M2L4(NO3)(H2O)(3)][Dy2M2L4(NO3)(CH3COO)-(H2O)(2)]center dot NO3 center dot 12H(2)O center dot 2C(2)H(5)OH}(n) [M = Ni (1); Co (2)] have been prepared using the multidentate ligand 2-{[(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzoic acid (H2L), which has NO and OO' chelating pockets that are able to selectively encapsulate Ln(III) and transition metal ions, respectively. Crystal structure analyses reveal that the two complexes are isostructural and display one-dimensional ladder like double helical chain structures, in which the two single helical chains {[Dy2M2L4(NO3)(H2O)(3)](+)} and {Dy2M2L4(NO3)(CH3COO)(H2O)(2)} (M = Ni(1), Co(2)) both run along the c-axis and have opposite chirality. Complexes 1 and 2 represent the first example of 3d-4f double-chain frameworks in which the compositions of the two individual chains are different. Variable temperature dc magnetic susceptibility studies reveal different strengths of ferromagnetic interactions between the magnetic centers in 1 and 2, which is mainly attributed to the different metal centers and finally results in the distinctive magnetic dynamic behaviors. |
| WOS关键词 | SINGLE-MOLECULE-MAGNET ; ANISOTROPY BARRIER ; COMPLEXES ; DY ; BEHAVIOR ; GD ; LN ; TB ; DYNAMICS ; CLUSTERS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000379352900038 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6338]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China |
| 推荐引用方式 GB/T 7714 | She, Shixiong,Li, Yahong,Li, Wu. Two 3d-4f double helical chains including [Dy2M2](n) (M = Ni-II and Co-II) cores exhibiting slow magnetic relaxation[J]. DALTON TRANSACTIONS,2016,45(26):10830-10835. |
| APA | She, Shixiong,Li, Yahong,&Li, Wu.(2016).Two 3d-4f double helical chains including [Dy2M2](n) (M = Ni-II and Co-II) cores exhibiting slow magnetic relaxation.DALTON TRANSACTIONS,45(26),10830-10835. |
| MLA | She, Shixiong,et al."Two 3d-4f double helical chains including [Dy2M2](n) (M = Ni-II and Co-II) cores exhibiting slow magnetic relaxation".DALTON TRANSACTIONS 45.26(2016):10830-10835. |
入库方式： OAI收割
来源：青海盐湖研究所
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