Water Activity, Solubility Determination, and Model Simulation of the CaCl2-SrCl2-H2O Ternary System at 323.15 K
文献类型：期刊论文
| 作者 | Han, Haijun1,2; Ji, Xiang3; Ma, Junjie1; Xu, Zhifeng1; Guo, Lijiang2; Li, Dongdong2 ; Yao, Yan2
|
| 刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 63期号:5页码:1636-1641 |
| 文献子类 | Article |
| 英文摘要 | Water activities for the CaCl2-SrCl2-H2O ternary system and its sub-binary system were elaborately determined using an isopiestic vapor-pressure method at 323.15 K. The solubility of the titled ternary system at 323.15 K was also determined by the isothermal equilibrium method. The Pitzer-Simonson-Clegg (PSC) model was used for correlating the determined water activity and solubility data, simulating the thermodynamic properties, and predicting the solubility isotherm of the titled system. The reliability of the determined solubility results in this work was evaluated by comparing with the solubility isotherms calculated with the PSC model. The model simulation results showed that the thermodynamic properties and solubility can be predicted with binary parameters only. The experiment and simulation results showed that the equilibrium solid phase in the CaCl2-SrCl2-H2O ternary system are pure salts, and no solid solution was found at 323.15 K. |
| WOS关键词 | ISOPIESTIC MEASUREMENT ; PHASE-EQUILIBRIA ; THERMODYNAMICS ; KCL-SRCL2-H2O ; 25-DEGREES-C |
| WOS研究方向 | Thermodynamics ; Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000432206100056 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6710]  |
| 专题 | 中国科学院青海盐湖研究所 |
| 通讯作者 | Xu, Zhifeng; Guo, Lijiang |
| 作者单位 | 1.Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China 3.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Haijun,Ji, Xiang,Ma, Junjie,et al. Water Activity, Solubility Determination, and Model Simulation of the CaCl2-SrCl2-H2O Ternary System at 323.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2018,63(5):1636-1641. |
| APA | Han, Haijun.,Ji, Xiang.,Ma, Junjie.,Xu, Zhifeng.,Guo, Lijiang.,...&Yao, Yan.(2018).Water Activity, Solubility Determination, and Model Simulation of the CaCl2-SrCl2-H2O Ternary System at 323.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,63(5),1636-1641. |
| MLA | Han, Haijun,et al."Water Activity, Solubility Determination, and Model Simulation of the CaCl2-SrCl2-H2O Ternary System at 323.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 63.5(2018):1636-1641. |
入库方式： OAI收割
来源：青海盐湖研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。