中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Surface modification of magnesium hydroxide sulfate hydrate whiskers using a silane coupling agent by dry process

文献类型:期刊论文

作者Zhu, Donghai1,2; Nai, Xueying1,2; Lan, Shengjie1,2,3; Bian, Shaoju1,2,3; Liu, Xin1,2; Li, Wu1,2
刊名APPLIED SURFACE SCIENCE
出版日期2016-12-30
卷号390页码:25-30
关键词Magnesium Hydroxide Sulfate Hydrate Whiskers Silane Surface Modification Dry Process
文献子类Article
英文摘要In order to improve the compatibility of magnesium hydroxide sulfate hydrate (MHSH) whiskers with polymers, the surface of MHSH whiskers was modified using vinyltriethoxysilane (VTES) by dry process. The possible mechanism of the surface modification and the interfacial interactions between MHSH whiskers and VTES, as well as the effect of surface modification, were studied. Scanning electronic microscopy (SEM), transmission electron microscopy (TEM) and X-ray powder diffraction (XRD) analyses showed that the agglomerations were effectively separated and a thin layer was formed on the surface of the whiskers after modification. Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS) analyses showed that the VTES molecules were bound to the surface of MHSH whiskers after modification. Chemical bonds (Si-O-Mg) were formed by the reaction between Si-OC2H5 or Si-OH and the hydroxyl group of MHSH whiskers. The effect of surface modification was evaluated by sedimentation tests, contact angle measurements and thermogravimetric analysis (TGA). The results showed that the surface of MHSH whiskers was transformed from hydrophilic to hydrophobic, and the dispersibility and the compatibility of MHSH whiskers were significantly improved in the Organic phase. Additionally, the thermal stability of the VTES-modified MHSH whiskers was improved significantly. (C) 2016 Elsevier B.V. All rights reserved.
WOS关键词OXYSULFATE WHISKERS ; HYDROTHERMAL FORMATION ; PERFORMANCE ; MECHANISM
WOS研究方向Chemistry ; Materials Science ; Physics
语种英语
WOS记录号WOS:000385900700004
源URL[http://ir.isl.ac.cn/handle/363002/6358]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Chinese Acad Sci, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Donghai,Nai, Xueying,Lan, Shengjie,et al. Surface modification of magnesium hydroxide sulfate hydrate whiskers using a silane coupling agent by dry process[J]. APPLIED SURFACE SCIENCE,2016,390:25-30.
APA Zhu, Donghai,Nai, Xueying,Lan, Shengjie,Bian, Shaoju,Liu, Xin,&Li, Wu.(2016).Surface modification of magnesium hydroxide sulfate hydrate whiskers using a silane coupling agent by dry process.APPLIED SURFACE SCIENCE,390,25-30.
MLA Zhu, Donghai,et al."Surface modification of magnesium hydroxide sulfate hydrate whiskers using a silane coupling agent by dry process".APPLIED SURFACE SCIENCE 390(2016):25-30.

入库方式: OAI收割

来源:青海盐湖研究所

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