Synthesis of MgO nanocrystals with abundant surface defects via a carbonization method employing CO2 gas as starting material
文献类型：期刊论文
| 作者 | Hai, Chunxi1,2 ; Zhou, Yuan1,2; Du, Yongsheng1,2; Sun, Yanxia1,2,3; Zeng, Jinbo1,2; Shen, Yue1,2; Ren, Xiufeng1,2,3; Li, Xiang1,2; Zhang, Lijuan1,2,3; Dong, Ouyang1,2
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| 刊名 | MATERIALS RESEARCH BULLETIN
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| 出版日期 | 2017 |
| 卷号 | 85页码:181-187 |
| 关键词 | Nanostructures Semiconductors Optical Properties Crystal Growth Surface Properties |
| 文献子类 | Article |
| 英文摘要 | Taking its unique property into consideration, uniformly dispersed MgO nanoparticles with abundant surface oxygen defects was primarily synthesized via a facile carbnization method employing CO2 gas as carburizer in this study. After reaction at 60 degrees C for 2 h, Mg2+ ions were totally carbonized to caterpillar-like Mg-5(CO3)(4)(OH)(2)(H2O)(4) precursor. And through decarbonization and dehydration processes during calcination, as-prepared Mg-5(CO3)(4)(OH)(2) (H2O)(4) precursor with micro-nano structure was thouroughly converted to well-crystallized MgO nanospheres. As-evidenced by the UV-VIS-NIR diffuse reflectance spectroscopy, due to the largely intensified low-coordinated oxide ions at the corner and kink sites with decreasing the average size, the forbidden band gap of as-prepared MgO nanocrystals is 5.3 eV, which thus endows it intriguing applications in different fields. (C) 2016 Elsevier Ltd. All rights reserved. |
| WOS关键词 | MAGNESIUM-OXIDE ; FACILE SYNTHESIS ; CATALYTIC-ACTIVITY ; OPTICAL-PROPERTIES ; PERFORMANCE ; PRECIPITATION ; NANOSHEETS ; DEVICES |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000387630600024 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6368]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Effieicent Utilizat S, 18th Xinning Rd, Xining 810008, Peoples R China 2.Key Lab Salt Lake Resources Chem Qinghai Prov, Golmud City, Qinghai Provinc, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hai, Chunxi,Zhou, Yuan,Du, Yongsheng,et al. Synthesis of MgO nanocrystals with abundant surface defects via a carbonization method employing CO2 gas as starting material[J]. MATERIALS RESEARCH BULLETIN,2017,85:181-187. |
| APA | Hai, Chunxi.,Zhou, Yuan.,Du, Yongsheng.,Sun, Yanxia.,Zeng, Jinbo.,...&Dong, Ouyang.(2017).Synthesis of MgO nanocrystals with abundant surface defects via a carbonization method employing CO2 gas as starting material.MATERIALS RESEARCH BULLETIN,85,181-187. |
| MLA | Hai, Chunxi,et al."Synthesis of MgO nanocrystals with abundant surface defects via a carbonization method employing CO2 gas as starting material".MATERIALS RESEARCH BULLETIN 85(2017):181-187. |
入库方式： OAI收割
来源：青海盐湖研究所
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