Effects of pH and salinity on the separation of magnesium and lithium from brine by nanofiltration
文献类型：期刊论文
| 作者 | Li, Yan1,2,3; Zhao, Youjing1,2 ; Wang, Min1,2
|
| 刊名 | DESALINATION AND WATER TREATMENT
 |
| 出版日期 | 2017-11-01 |
| 卷号 | 97页码:141-150 |
| 关键词 | Nanofiltration Separation Of mg2+/li+ Salinity Ph |
| 文献子类 | Article |
| 英文摘要 | It is difficult to extract lithium because of the high ratio of Mg2+ and Li+ in most salt lake brines in China. Therefore, the separation process of high Mg2+/Li+ ratio salt lake brine by a negatively charged DK nanofiltration membrane was investigated. The stability of the nanofiltration membrane, the concentration polarization phenomenon, and the surface charge of the nanofiltration membrane was first explored. The ability of the membrane to separate Mg2+ and Li+ at different salinities and pHs was further evaluated. The results indicate that due to the viscosity variation of the solution and the concentration polarization phenomenon, the membrane flux decreases with rising salinity. The Donnan exclusion, dielectric exclusion, and steric hindrance were studied to characterize the ionic fractionations of the nanofiltration membrane. When the salinity was 35 g/L, the Mg2+/Li+ reduced to 1.49. The membrane flux remained constant at different pHs, and the retention factor of Mg2+ was always higher than that of Li+. It remained at a relatively high level because of the electrostatic interaction between the cations and the negative charge on the functional groups on the membrane surface. The difference of the cation characters makes the retention factor of Mg2+ higher. The separation effect was relatively better under lower pH conditions. |
| WOS关键词 | DIELECTRIC EXCLUSION MODEL ; SALT LAKE BRINE ; REVERSE-OSMOSIS ; MASS-TRANSFER ; CONCENTRATION POLARIZATION ; ELECTROLYTE TRANSPORT ; MEMBRANE PERFORMANCE ; CHARGE ; RECOVERY ; NF |
| WOS研究方向 | Engineering ; Water Resources |
| 语种 | 英语 |
| WOS记录号 | WOS:000423705900014 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6376]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China 2.Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Qinghai, Peoples R China 3.Univ Chinese Acad Sci, Beijing 101408, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yan,Zhao, Youjing,Wang, Min. Effects of pH and salinity on the separation of magnesium and lithium from brine by nanofiltration[J]. DESALINATION AND WATER TREATMENT,2017,97:141-150. |
| APA | Li, Yan,Zhao, Youjing,&Wang, Min.(2017).Effects of pH and salinity on the separation of magnesium and lithium from brine by nanofiltration.DESALINATION AND WATER TREATMENT,97,141-150. |
| MLA | Li, Yan,et al."Effects of pH and salinity on the separation of magnesium and lithium from brine by nanofiltration".DESALINATION AND WATER TREATMENT 97(2017):141-150. |
入库方式： OAI收割
来源：青海盐湖研究所
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