Full N, N-Methylation of 4,4 '-Methylenedianiline with Dimethyl Carbonate: A Feasible Access to 4,4 '-Methylene bis(N, N-Dimethylaniline)
文献类型：期刊论文
| 作者 | Qiu, Zegang1; Wang, Kunjie2; Li, Zhiqin1; Li, Tao1; Bai, Jinhao1; Yin, Chanjuan1; Ye, Xiushen3 ; Liu, Haining3
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| 刊名 | JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2018 |
| 文献子类 | Article |
| 英文摘要 | The full N, N-methylation of 4,4'-methylenedianiline (MDA) with dimethyl carbonate (DMC) was investigated. The yield of the major product 4,4'-methylene bis(N, N-dimethylaniline) (MBDMA) reached as high as 97% over NaY catalyst at 190 degrees C for 6h. The catalyst could be used for two more times with acceptable MBDMA yields higher than 90%. The main by-products were identified as three N-methylated derivatives. Surprisingly, the formation of the N-methoxycarbonylation product was extremely restrained, which could be produced in high yields of 98% on zinc acetate catalyst. Furthermore, the reaction pathway to the major product MBDMA was proposed. Finally, a feasible synthetic route of 4,4'-methylene bis(N, N-dimethylaniline) (MBDMA) was established, featuring a high yield, mild reaction conditions, and simple operations. |
| WOS关键词 | PHOTOINDUCED ELECTRON-TRANSFER ; FUNCTIONALIZED ANILINES ; NAY FAUJASITE ; ZINC ACETATE ; AMINES ; METHOXYCARBONYLATION ; SELECTIVITY ; CATALYSTS ; KINETICS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000431322000001 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/6465]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 青海盐湖研究所_盐湖资源与化学实验室 |
| 作者单位 | 1.Xian Shiyou Univ, Coll Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China 2.Xian Aerosp Composites Res Inst, Xian 710025, Shaanxi, Peoples R China 3.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Zegang,Wang, Kunjie,Li, Zhiqin,et al. Full N, N-Methylation of 4,4 '-Methylenedianiline with Dimethyl Carbonate: A Feasible Access to 4,4 '-Methylene bis(N, N-Dimethylaniline)[J]. JOURNAL OF CHEMISTRY,2018. |
| APA | Qiu, Zegang.,Wang, Kunjie.,Li, Zhiqin.,Li, Tao.,Bai, Jinhao.,...&Liu, Haining.(2018).Full N, N-Methylation of 4,4 '-Methylenedianiline with Dimethyl Carbonate: A Feasible Access to 4,4 '-Methylene bis(N, N-Dimethylaniline).JOURNAL OF CHEMISTRY. |
| MLA | Qiu, Zegang,et al."Full N, N-Methylation of 4,4 '-Methylenedianiline with Dimethyl Carbonate: A Feasible Access to 4,4 '-Methylene bis(N, N-Dimethylaniline)".JOURNAL OF CHEMISTRY (2018). |
入库方式： OAI收割
来源：青海盐湖研究所
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