A study on the ignition process for the catalytic partial oxidation of methane to synthesis gas by MS-TPSR technique
文献类型:期刊论文
| 作者 | Ji, YY; Li, WZ; Xu, HY; Chen, YX |
| 刊名 | catalysis letters
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| 出版日期 | 2001 |
| 卷号 | 71期号:1-2页码:45-48 |
| 关键词 | ignition process catalytic partial oxidation of methane fluidized bed |
| 英文摘要 | the ignition processes for the catalytic partial oxidation of methane (pom) to synthesis gas over oxidic nickel catalyst (nio/al2o3), reduced nickel catalyst (ni-0/al2o3), and pt-promoted oxidic nickel catalyst (pt-nio/al2o3) were studied by the temperature-programmed surface reaction (tpsr) technique. the complete oxidation of methane usually took place on the nio catalyst during the ch4/o-2 reaction, even with a pre-reduced nickel catalyst, and ni-0 is inevitably first oxidized to nio if the temperature is below the ignition temperature. it is above a certain temperature that ni-0 is formed again, which leads to the start of the pom. the pom can be initiated at a much lower temperature on a pt-nio catalyst because of pt promotion of the reduction of nio. the pom in a fluidized bed can be easily initiated due to the addition of pt. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | fluidized-bed reactor ; ni/al2o3 catalyst ; carbon-monoxide ; conversion ; syngas ; hydrogen |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000168379800008 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/84309] ![]() |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, YY,Li, WZ,Xu, HY,et al. A study on the ignition process for the catalytic partial oxidation of methane to synthesis gas by MS-TPSR technique[J]. catalysis letters,2001,71(1-2):45-48. |
| APA | Ji, YY,Li, WZ,Xu, HY,&Chen, YX.(2001).A study on the ignition process for the catalytic partial oxidation of methane to synthesis gas by MS-TPSR technique.catalysis letters,71(1-2),45-48. |
| MLA | Ji, YY,et al."A study on the ignition process for the catalytic partial oxidation of methane to synthesis gas by MS-TPSR technique".catalysis letters 71.1-2(2001):45-48. |
入库方式: OAI收割
来源:大连化学物理研究所
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