Nucleation and morphology of sodium molybdate dihydrate from NaOH solution
文献类型：期刊论文
| 作者 | Liu, Yan1; Zou, Xingwu2,3; Duan, Dongping1; Luo, Lijie4; Chen, Siming1; Zhong, Li1 |
| 刊名 | JOURNAL OF CRYSTAL GROWTH
 |
| 出版日期 | 2019-01-15 |
| 卷号 | 506页码:102-107 |
| 关键词 | Crystal morphology Nucleation Sodium molybdate dihydrate Induction time Growth mechanism |
| ISSN号 | 0022-0248 |
| DOI | 10.1016/j.jcrysgro.2018.10.006 |
| 英文摘要 | The induction time for sodium molybdate dihydrate crystallization from NaOH solution at 40 degrees C and 60 degrees C was investigated by experiment and the primary nucleation was also identified according to the classical nucleation theory. The bipyramidal truncated crystals and the nearly rectangular parallelepiped crystals were obtained at high supersaturation and low supersaturation, respectively. The interfacial free energy, surface entropy factor, critical nucleation free energy, critical nucleus size and critical nucleation molecular number of bipyramidal truncated crystals were conducted. The nearly rectangular parallelepiped crystals are considered more stable than the bipyramidal truncated crystals, and high supersaturation and high temperature are more conducive to nucleation of sodium molybdate dihydrate crystals. Finally, the normal growth mechanism for Na2MoO4 center dot 2H(2)O crystallization was identified with various models and the surface entropy factor. |
| WOS关键词 | GROWTH-MECHANISM ; INDUCTION TIME ; PRECIPITATION ; PHOSPHATE ; SYSTEM |
| WOS研究方向 | Crystallography ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000449709600017 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/26583]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Yan |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Qinghai, Peoples R China 3.Qinghai Engn & Technol Res Ctr Comprehens Utiliza, Xining 810008, Qinghai, Peoples R China 4.Hainan Univ, Coll Mat & Chem Engn, Haikou 570228, Hainan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yan,Zou, Xingwu,Duan, Dongping,et al. Nucleation and morphology of sodium molybdate dihydrate from NaOH solution[J]. JOURNAL OF CRYSTAL GROWTH,2019,506:102-107. |
| APA | Liu, Yan,Zou, Xingwu,Duan, Dongping,Luo, Lijie,Chen, Siming,&Zhong, Li.(2019).Nucleation and morphology of sodium molybdate dihydrate from NaOH solution.JOURNAL OF CRYSTAL GROWTH,506,102-107. |
| MLA | Liu, Yan,et al."Nucleation and morphology of sodium molybdate dihydrate from NaOH solution".JOURNAL OF CRYSTAL GROWTH 506(2019):102-107. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。