Measurement and Correlation of the Solubility of Florfenicol Form A in Several Pure and Binary Solvents
文献类型：期刊论文
| 作者 | Zhang, PS; Zhang, C; Zhao, R; Wan, YM; Yang, ZK; He, RY; Chen, QL; Li, T; Ren, BZ; Zhang, Pengshuai |
| 刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| 出版日期 | 2018 |
| 卷号 | 63期号:6页码:2046 |
| 关键词 | LIQUID-MIXTURES WATER ACIDS |
| ISSN号 | 0021-9568 |
| DOI | 10.1021/acs.jced.8b00043 |
| 文献子类 | Article |
| 英文摘要 | The solubility of florfenicol form A in eight pure organic solvents (propionic acid, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-methyl-1-propanol, 3-methyl-1-butanol, and 2-ethyl-1-hexanol) and three binary solvents (dimethyl sulfoxide + ethanol, dimethyl sulfoxide + 1-propanol, and dimethyl sulfoxide + 1-butanol) was measured by a laser dynamic method at temperature from 283.15 to 323.15 K. The experimental results show that the mole fraction solubility of florfenicol in the pure solvents decreased according to the following order: ethanol > 1-propanol > 2-propanol > 1-butanol > 3-methyl-1-butanol > 2-methyl-1-propanol propionic acid > 2-ethyl-1-hexanol. The experimental results show that the mole fraction solubility of florfenicol form A in the binary solvents increased with the increase of temperature and dimethyl sulfoxide mass fraction. The experimental solubility data were well correlated with the four thermodynamic models: modified Apelblat equation, lambda h equation, NRTL model equation, and Wilson model equation. The modified Apelblat model equation was regarded as the best one to fit the experimental values in the pure solvents. |
| WOS记录号 | WOS:000435613000023 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/26757]  |
| 专题 | 中国科学院过程工程研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, PS,Zhang, C,Zhao, R,et al. Measurement and Correlation of the Solubility of Florfenicol Form A in Several Pure and Binary Solvents[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2018,63(6):2046, 2055. |
| APA | Zhang, PS.,Zhang, C.,Zhao, R.,Wan, YM.,Yang, ZK.,...&Ren, Baozeng.(2018).Measurement and Correlation of the Solubility of Florfenicol Form A in Several Pure and Binary Solvents.JOURNAL OF CHEMICAL AND ENGINEERING DATA,63(6),2046. |
| MLA | Zhang, PS,et al."Measurement and Correlation of the Solubility of Florfenicol Form A in Several Pure and Binary Solvents".JOURNAL OF CHEMICAL AND ENGINEERING DATA 63.6(2018):2046. |
入库方式： OAI收割
来源：过程工程研究所
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