Thermodynamic analysis and correlation of cyromazine in three (acetic acid, propanoic acid or ethylene glycol plus water) binary solvents at different temperatures
文献类型：期刊论文
| 作者 | Zhang, PS; Zhao, R; Zhang, C; Wan, YM; Li, T; Ren, BZ; Zhang, Pengshuai; Zhao, Rui; Zhang, Chi; Wan, Yameng |
| 刊名 | JOURNAL OF MOLECULAR LIQUIDS
 |
| 出版日期 | 2018 |
| 卷号 | 272页码:158 |
| 关键词 | MATHEMATICAL REPRESENTATION ORGANIC-SOLVENTS PURE SOLVENTS SOLUBILITY METHANOL MAGNESIUM MIXTURES CALCIUM ETHANOL MODELS |
| ISSN号 | 0167-7322 |
| DOI | 10.1016/j.molliq.2018.09.047 |
| 文献子类 | Article |
| 英文摘要 | The solubility of cyromazine in three binary solvent mixtures (acetic acid + water, propanoic acid + water, ethylene glycol + water) were measured by a gravimetric method from 278.15 K to 333.15 K under atmospheric pressure. The experimental results reveal that the mole fraction solubility of cyromazine increased with the increase of temperature in the three solvents. The Apelblat equation, the lambda h equation, the general single model (GSM) equation and the modified Jouyban-Acree model equation were all applied to correlate the experimental solubility of cyromazine well. Moreover, the dissolution thermodynamic properties: Delta solHP0 (the apparent standard enthalpy change), Delta S-sol(0) (the apparent standard entropy change), Delta(sol)G(0) (the apparent standard Gibbs energy change), zeta(H) (relative contribution of enthalpy) and zeta(TS) (relative contribution of entropy) of the dissolution of cyromazine in the selected solvents were calculated. The positive values of Delta H-sol(0), Delta(sol)G(0),zeta(H) >= 0.5984 and zeta(rs) <= 0.4016 indicated that the dissolution of cyromazine in the three binary solvents was enthalpy-driving and endothermic process. The experimental solubility of cyromazine in this work can provide good guidance and fundamental data for the crystallization, purification and application of cyromazine. (C) 2018 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000451494700017 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/26765]  |
| 专题 | 中国科学院过程工程研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, PS,Zhao, R,Zhang, C,et al. Thermodynamic analysis and correlation of cyromazine in three (acetic acid, propanoic acid or ethylene glycol plus water) binary solvents at different temperatures[J]. JOURNAL OF MOLECULAR LIQUIDS,2018,272:158, 169. |
| APA | Zhang, PS.,Zhao, R.,Zhang, C.,Wan, YM.,Li, T.,...&Ren, Baozeng.(2018).Thermodynamic analysis and correlation of cyromazine in three (acetic acid, propanoic acid or ethylene glycol plus water) binary solvents at different temperatures.JOURNAL OF MOLECULAR LIQUIDS,272,158. |
| MLA | Zhang, PS,et al."Thermodynamic analysis and correlation of cyromazine in three (acetic acid, propanoic acid or ethylene glycol plus water) binary solvents at different temperatures".JOURNAL OF MOLECULAR LIQUIDS 272(2018):158. |
入库方式： OAI收割
来源：过程工程研究所
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