Confronting issues of silicon-based anode for its huge volume change (similar to 320%), porous silicon attracts note-worthy attention. Most previous studies are concentrated on designing various sacrificial templates to endow silicon with marvelous shapes or structures. Herein, without the assistance of sacrificial template, a template-free method is developed to fabricate interpenetrated three-dimensional porous silicon. A silica composite gel, which possesses numerous nano-pores, is primarily constructed, and the silicon can be inherently equipped with these nano-pores via modified magnesiothermic reduction. Scanning electron microscope and transmission electron microscope images illustrate that the as-prepared porous silicon possesses bi-continuous structure. It also exhibits high initial reversible capacity (similar to 1.41 mAh cm(-2) at 0.16 mA cm(-2)), superior cycling stability (similar to 0.98 mAh cm(-2) after 200 cycles), and good rate performance. In addition, analysis of cyclic voltammetry curves and electrochemical impedance spectroscopy demonstrate that this porous silicon possesses appropriate channels for rapid Li(+ )transport and low electrochemical reaction polarization resistance.