Synthesis, characterization and electrochemical properties of S-doped carbon aerogels
文献类型:期刊论文
作者 | Xu, YL; Wang, SS; Yan, MF; Zhang, LH; Liu, ZF; Xu, Yuelong; Wang, Shasha; Yan, Meifang; Zhang, Lihui; Liu, Zhenfa |
刊名 | SOLID STATE IONICS
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出版日期 | 2018 |
卷号 | 321页码:91 |
关键词 | S-doping WASTE-WATER Carbon aerogels PERFORMANCE Sodium 4-hydroxybenzenesulfonate NANOCOMPOSITES Electrochemical properties SUPERCAPACITORS Textural properties NANOSTRUCTURE FORMALDEHYDE COMPOSITE CATALYSTS REMOVAL CELLS |
ISSN号 | 0167-2738 |
DOI | 10.1016/j.ssi.2018.04.009 |
文献子类 | Article |
英文摘要 | Heteroatom doping in carbon aerogels is critical for improving the surface areas and electronic properties of these aerogels. This paper demonstrates doping sulfur (S) atom into carbon aerogels. S-doped carbon aerogels (SCAs) were prepared via a sol-gel process using phloroglucinol (P), resorcinol (R) and formaldehyde as the polymerization precursors with sodium carbonate (Na2CO3) as the basic catalyst and sodium 4-hydroxybenzenesulfonate (HBS) as the surfactant. The as-synthesized products were dried in normal temperature and carbonized with temperature-programmed. The effects of S-doping on the surface area and electronic properties of the S-CAs were studied by a surface area analyzer and electrochemical workstation. When the S loading was up to 1.38%, the corresponding S-CA exhibited the most optimal surface area and specific capacitance. The textural properties were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), a surface area analyzer, an X-ray diffraction spectrometer, a Raman spectrometer, the X-ray photoelectron spectroscopy (XPS) spectra, an elemental analyzer and an EDX detector, and the electrochemical properties were measured using cyclic voltammetry, galvanostatic charge-discharge measurements and electrochemical impedance spectroscopy (EIS). When the molar ratio of HBS/(P + R) was 0.05, the S loading was 1.38%, the specific surface area of the as-synthesized CA was 831 m(2)/g, and its specific capacitance was 105 F/g, |
WOS记录号 | WOS:000437372200014 |
源URL | [http://ir.ipe.ac.cn/handle/122111/26803] ![]() |
专题 | 中国科学院过程工程研究所 |
推荐引用方式 GB/T 7714 | Xu, YL,Wang, SS,Yan, MF,et al. Synthesis, characterization and electrochemical properties of S-doped carbon aerogels[J]. SOLID STATE IONICS,2018,321:91, 97. |
APA | Xu, YL.,Wang, SS.,Yan, MF.,Zhang, LH.,Liu, ZF.,...&Liu, Zhenfa.(2018).Synthesis, characterization and electrochemical properties of S-doped carbon aerogels.SOLID STATE IONICS,321,91. |
MLA | Xu, YL,et al."Synthesis, characterization and electrochemical properties of S-doped carbon aerogels".SOLID STATE IONICS 321(2018):91. |
入库方式: OAI收割
来源:过程工程研究所
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