A potassium-rich iron hexacyanoferrate/dipotassium terephthalate@carbon nanotube composite used for K-ion full-cells with an optimized electrolyte
文献类型:期刊论文
作者 | Liao, Jiaying1; Hu, Qiao1; Yu, Yingtao1; Wang, Heyang1; Tang, Zhongfeng1; Wen, Zhaoyin2; Chen, Chunhua1 |
刊名 | Journal of Materials Chemistry A
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出版日期 | 2017 |
卷号 | 5期号:36页码:19017-19024 |
ISSN号 | 20507488 |
DOI | 10.1039/c7ta05460b |
英文摘要 | K-ion batteries, as an emerging battery system, have attracted tremendous attention in the research community. Herein, we report a K-ion full-cell based on a nano-sized K1.92Fe[Fe(CN)6]0.94·0.5H2O cathode, dipotassium terephthalate (K2TP)@carbon nanotube (CNT) anode and an optimized electrolyte. K1.92Fe[Fe(CN)6]0.94·0.5H2O delivers a high capacity of 133 mA h g-1with 92.8% capacity retention after 200 cycles and high coulombic efficiency of 98.5%. The side reactions of K metal with the electrolyte are suppressed in KClO4/propylene carbonate (PC). The K2TP nanosheets grown in situ on the CNT show a high reversible capacity of about 250 mA h g-1and an ultra-high rate capability. The full-cells based on them are well cycled in a DME-based electrolyte and show a great promise for large-scale energy storage. © 2017 The Royal Society of Chemistry. |
源URL | [http://ir.sic.ac.cn/handle/331005/25905] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.CAS Key Laboratory of Materials for Energy Conversions, Department of Materials Science and Engineering, Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei, Anhui; 230026, China; 2.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China |
推荐引用方式 GB/T 7714 | Liao, Jiaying,Hu, Qiao,Yu, Yingtao,et al. A potassium-rich iron hexacyanoferrate/dipotassium terephthalate@carbon nanotube composite used for K-ion full-cells with an optimized electrolyte[J]. Journal of Materials Chemistry A,2017,5(36):19017-19024. |
APA | Liao, Jiaying.,Hu, Qiao.,Yu, Yingtao.,Wang, Heyang.,Tang, Zhongfeng.,...&Chen, Chunhua.(2017).A potassium-rich iron hexacyanoferrate/dipotassium terephthalate@carbon nanotube composite used for K-ion full-cells with an optimized electrolyte.Journal of Materials Chemistry A,5(36),19017-19024. |
MLA | Liao, Jiaying,et al."A potassium-rich iron hexacyanoferrate/dipotassium terephthalate@carbon nanotube composite used for K-ion full-cells with an optimized electrolyte".Journal of Materials Chemistry A 5.36(2017):19017-19024. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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