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Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2

文献类型：期刊论文

作者Feng, Aihu1,2; Yu, Yun1; Wang, Yong1,2; Jiang, Feng1,2; Yu, Yang1; Mi, Le1; Song, Lixin1
刊名Materials and Design
出版日期2017
卷号114页码:161-166
ISSN号02641275
DOI10.1016/j.matdes.2016.10.053
英文摘要MXene, a new family of 2D materials, possesses excellent electrical conductivity and hydrophilicity. To date, the majority of MXenes are only successfully produced by exfoliating the MAX phases with high concentration hydrofluoric acid (HF). In this study, the 2D MXene Ti3C2with larger interplanar spacing was successfully obtained by etching Ti3AlC2with bifluoride (NaHF2, KHF2, NH4HF2) in single-stage process. The morphology, structure and element composition of prepared Ti3C2samples were characterized by scanning electron smicroscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectrometer (EDS). The synthesis mechanism of Ti3C2was elaborately demonstrated. The possible reaction equations between Ti3AlC2and different bifluorides were generalized, indicating the formation of hydrosoluble by-products of Na3AlF6,K3AlF6and (NH4)3AlF6. This work presents a safely effective method to synthesize the 2D nanocrystals MXene. © 2016 Elsevier Ltd
源URL[http://ir.sic.ac.cn/handle/331005/25856]  
专题中国科学院上海硅酸盐研究所
作者单位1.Key Laboratory of Inorganic Coating Materials CAS, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China;
2.University of Chinese Academy of Sciences, Beijing; 100049, China
推荐引用方式
GB/T 7714		 Feng, Aihu,Yu, Yun,Wang, Yong,et al. Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2[J]. Materials and Design,2017,114:161-166.
APA Feng, Aihu.,Yu, Yun.,Wang, Yong.,Jiang, Feng.,Yu, Yang.,...&Song, Lixin.(2017).Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2.Materials and Design,114,161-166.
MLA Feng, Aihu,et al."Two-dimensional MXene Ti3C2produced by exfoliation of Ti3AlC2".Materials and Design 114(2017):161-166.

入库方式： OAI收割

来源：上海硅酸盐研究所

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