A study on the structure, luminescence and thermo-stability of polycrystalline Gd2Si2O7:Ce and (Gd,La)2Si2O7:Ce
文献类型：期刊论文
| 作者 | Wei, Qinhua1; Shi, Hongsheng1; Zhou, Zhenzhen2; Liu, Guanghui2; Chen, Zhi1; Qin, Laishun1; Shu, Kangying1; Liu, Qian2 |
| 刊名 | Journal of Materials Chemistry C
 |
| 出版日期 | 2017 |
| 卷号 | 5期号:6页码:1443-1451 |
| ISSN号 | 20507534 |
| DOI | 10.1039/c6tc04484k |
| 英文摘要 | Gd2Si2O7:Ce (GPS:Ce) and (Gd,La)2Si2O7:Ce (La-GPS:Ce) phosphors with different crystal structures, tetragonal, orthorhombic and triclinic, were synthesized via a sol-gel technique. The prepared samples have been systematically investigated using room temperature (RT) XRD, high temperature (HT) XRD, HRTEM, selected area electron diffraction (SAED) and EDS elemental analysis. The results show that the phase transition occurred at 1350-1450 °C and the tetragonal phase was a low-temperature metastable phase and the orthorhombic and triclinic structures were stable at high temperatures. It was observed that the three structures display completely different luminescence efficiencies under both UV lamp and X-ray excitation, but the decay time was not strongly dependent on the crystal structure. The luminescence thermo-stability and activation energy were also measured and calculated. The results indicate that the thermo-stability was strongly dependent on the crystal structure and the GPS:Ce-1500 °C sample showed the best thermo-stability. The three materials have potential application as a novel type of scintillator. © The Royal Society of Chemistry. |
| 源URL | [http://ir.sic.ac.cn/handle/331005/25820]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 作者单位 | 1.College of Materials Science & Engineering, China Jiliang University, Hangzhou; 310018, China; 2.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China |
| 推荐引用方式 GB/T 7714 | Wei, Qinhua,Shi, Hongsheng,Zhou, Zhenzhen,et al. A study on the structure, luminescence and thermo-stability of polycrystalline Gd2Si2O7:Ce and (Gd,La)2Si2O7:Ce[J]. Journal of Materials Chemistry C,2017,5(6):1443-1451. |
| APA | Wei, Qinhua.,Shi, Hongsheng.,Zhou, Zhenzhen.,Liu, Guanghui.,Chen, Zhi.,...&Liu, Qian.(2017).A study on the structure, luminescence and thermo-stability of polycrystalline Gd2Si2O7:Ce and (Gd,La)2Si2O7:Ce.Journal of Materials Chemistry C,5(6),1443-1451. |
| MLA | Wei, Qinhua,et al."A study on the structure, luminescence and thermo-stability of polycrystalline Gd2Si2O7:Ce and (Gd,La)2Si2O7:Ce".Journal of Materials Chemistry C 5.6(2017):1443-1451. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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