Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage
文献类型:期刊论文
作者 | Wang, Yongzhe1; Kong, Mingguang2; Liu, Ziwei1; Lin, Chucheng1; Zeng, Yi1 |
刊名 | Journal of Materials Chemistry A
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出版日期 | 2017 |
卷号 | 5期号:46页码:24269-24274 |
ISSN号 | 20507488 |
DOI | 10.1039/c7ta08264a |
英文摘要 | Co3O4/NiO/C microspheres with a multilayered ball-in-ball hollow nanoarchitecture were synthesized via carbonization and oxidation treatments of Morella-rubra-like CoNi-based metal-organic frameworks (CoNi-MOFs). The shell walls of each ball were entirely composed of uniform nanorods. This unique multilayered hollow structure can strongly mitigate the change in the volume of the electrodes, which maintains the structural integrity of the Co3O4/NiO/C hybrids during the lithiation-delithiation process. In addition, the C scaffolds improve the conductivity of the electrode and function as a buffer material to mitigate the pulverization of Co3O4and NiO nanoparticles. Therefore, in Li-ion cells, the multilayered Co3O4/NiO/C hybrids exhibit a high reversible capacity (864 mA h g-1at 1 A g-1), an excellent rate capacity (421 mA h g-1at 4 A g-1), and a long-lifetime cycling performance (776 mA h g-1, even after 1000 cycles at 1 A g-1) for Li storage. © The Royal Society of Chemistry 2017. |
源URL | [http://ir.sic.ac.cn/handle/331005/25610] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
作者单位 | 1.State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China; 2.Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Science, Hefei Anhui; 230031, China |
推荐引用方式 GB/T 7714 | Wang, Yongzhe,Kong, Mingguang,Liu, Ziwei,et al. Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage[J]. Journal of Materials Chemistry A,2017,5(46):24269-24274. |
APA | Wang, Yongzhe,Kong, Mingguang,Liu, Ziwei,Lin, Chucheng,&Zeng, Yi.(2017).Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage.Journal of Materials Chemistry A,5(46),24269-24274. |
MLA | Wang, Yongzhe,et al."Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage".Journal of Materials Chemistry A 5.46(2017):24269-24274. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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