中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage

文献类型:期刊论文

作者Wang, Yongzhe1; Kong, Mingguang2; Liu, Ziwei1; Lin, Chucheng1; Zeng, Yi1
刊名Journal of Materials Chemistry A
出版日期2017
卷号5期号:46页码:24269-24274
ISSN号20507488
DOI10.1039/c7ta08264a
英文摘要Co3O4/NiO/C microspheres with a multilayered ball-in-ball hollow nanoarchitecture were synthesized via carbonization and oxidation treatments of Morella-rubra-like CoNi-based metal-organic frameworks (CoNi-MOFs). The shell walls of each ball were entirely composed of uniform nanorods. This unique multilayered hollow structure can strongly mitigate the change in the volume of the electrodes, which maintains the structural integrity of the Co3O4/NiO/C hybrids during the lithiation-delithiation process. In addition, the C scaffolds improve the conductivity of the electrode and function as a buffer material to mitigate the pulverization of Co3O4and NiO nanoparticles. Therefore, in Li-ion cells, the multilayered Co3O4/NiO/C hybrids exhibit a high reversible capacity (864 mA h g-1at 1 A g-1), an excellent rate capacity (421 mA h g-1at 4 A g-1), and a long-lifetime cycling performance (776 mA h g-1, even after 1000 cycles at 1 A g-1) for Li storage. © The Royal Society of Chemistry 2017.
源URL[http://ir.sic.ac.cn/handle/331005/25610]  
专题中国科学院上海硅酸盐研究所
作者单位1.State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China;
2.Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Science, Hefei Anhui; 230031, China
推荐引用方式
GB/T 7714
Wang, Yongzhe,Kong, Mingguang,Liu, Ziwei,et al. Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage[J]. Journal of Materials Chemistry A,2017,5(46):24269-24274.
APA Wang, Yongzhe,Kong, Mingguang,Liu, Ziwei,Lin, Chucheng,&Zeng, Yi.(2017).Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage.Journal of Materials Chemistry A,5(46),24269-24274.
MLA Wang, Yongzhe,et al."Morella-rubra -like metal-organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage".Journal of Materials Chemistry A 5.46(2017):24269-24274.

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来源:上海硅酸盐研究所

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