The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction
文献类型：期刊论文
| 作者 | Xu DQ(徐大乾)1,2; Sun QS(孙强盛)2 ; Quan, Zhengjun1; Sun W(孙伟)2; Wang, Xicun1; Sun W(孙伟)
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| 刊名 | Tetrahedron: Asymmetry
 |
| 出版日期 | 2017 |
| 卷号 | 28期号:7页码:954-963 |
| ISSN号 | 0957-4166 |
| DOI | 10.1016/j.tetasy.2017.05.013 |
| 英文摘要 | A series of chiral tridentate ligands derived from readily available enantiopure L-proline were designed and synthesized. The ligands together with Cu(OAc)2 were successfully used in asymmetric Henry reactions. Various structurally divergent aldehydes and nitromethane were converted into versatile beta-nitro alcohols in MeOH at room temperature with very good yields (up to 85%) and enantioselectivities (up to 86%). |
| 学科主题 | 物理化学与绿色催化 |
| 资助项目 | 仿生与生物催化研究组 |
| 语种 | 英语 |
| WOS记录号 | WOS:000406571800008 |
| 资助机构 | the National Natural Science Foundation of China (21473226;21362031) |
| 源URL | [http://210.77.64.217/handle/362003/22441]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_苏州研究院 |
| 通讯作者 | Wang, Xicun; Sun W(孙伟) |
| 作者单位 | 1.College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, Gansu, China 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, and Suzhou Research Center of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China |
| 推荐引用方式 GB/T 7714 | Xu DQ,Sun QS,Quan, Zhengjun,et al. The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction[J]. Tetrahedron: Asymmetry,2017,28(7):954-963. |
| APA | Xu DQ,Sun QS,Quan, Zhengjun,Sun W,Wang, Xicun,&孙伟.(2017).The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction.Tetrahedron: Asymmetry,28(7),954-963. |
| MLA | Xu DQ,et al."The synthesis of chiral tridentate ligands from L-proline and their application in the copper(II)-catalyzed enantioselective Henry reaction".Tetrahedron: Asymmetry 28.7(2017):954-963. |
入库方式： OAI收割
来源：兰州化学物理研究所
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