Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex
文献类型：期刊论文
| 作者 | Pascale Maldivi9; Seungwoo Hong3,4; Jean-Marc Latour1,2,6; Ritimukta Sarangi8; Wonwoo Nam3,7; Mi Sook Seo3; Yong-Min Lee3; Lu, Xiaoyan3; Takehiro Ohta5; Takashi Ogura5 |
| 刊名 | Journal of the American Chemical Society
 |
| 出版日期 | 2017 |
| 卷号 | 139期号:41页码:14372-14375 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.7b08161 |
| 英文摘要 | A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]− (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C–H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1. |
| 学科主题 | 物理化学与绿色催化 |
| 语种 | 英语 |
| WOS记录号 | WOS:000413503300011 |
| 资助机构 | NRF of Korea through CRI (NRF-2012R1A3A2048842 to W.N.);GRL (NRF-2010-00353 t o W.N.);Basic Science Research Program (2017R1D1A1B03029982 to Y.M.L.);MSIP (NRF-2017R1C1B2002037 to S.H.);T.O. acknowledges the support of Grant-in-Aid for Scientific Research (No. 15H00960) by JSPS.;J.-M.L. and P.M. were supported by ANR (ANR-11-LABX-003); GENCI-IDRIS (Grant 2017-A0020807648);XAS data were measured at SSRL and R.S. was supported by NIH P41 grant (P41GM103393);DOE-BER |
| 源URL | [http://210.77.64.217/handle/362003/22738]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Pascale Maldivi; Jean-Marc Latour; Ritimukta Sarangi; Wonwoo Nam |
| 作者单位 | 1.Univ Grenoble Alpes, CNRS, UMR 5249, F-38054 Grenoble, France 2.Univ Grenoble Alpes, CEA BIG CBM, F-38054 Grenoble, France 3.Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea 4.Sookmyung Womens Univ, Dept Chem, Seoul 04310, South Korea 5.Univ Hyogo, Picobiol Inst, Grad Sch Life Sci, RSC UH LP Ctr, Mikazuki, Hyogo 6795148, Japan 6.Univ Grenoble Alpes, LCBM PMB, F-38054 Grenoble, France 7.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 8.SLAC Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA 9.Univ Grenoble Alpes, CNRS, CEA, INAC,SYMMES, F-38000 Grenoble, France |
| 推荐引用方式 GB/T 7714 | Pascale Maldivi,Seungwoo Hong,Jean-Marc Latour,et al. Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex[J]. Journal of the American Chemical Society,2017,139(41):14372-14375. |
| APA | Pascale Maldivi.,Seungwoo Hong.,Jean-Marc Latour.,Ritimukta Sarangi.,Wonwoo Nam.,...&Martin Clémancey.(2017).Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex.Journal of the American Chemical Society,139(41),14372-14375. |
| MLA | Pascale Maldivi,et al."Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex".Journal of the American Chemical Society 139.41(2017):14372-14375. |
入库方式： OAI收割
来源：兰州化学物理研究所
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