The roles of surface oxygen vacancy over Mg4Ta2O9-x photocatalyst in enhancing visible-light photocatalytic hydrogen evolution performance
文献类型:期刊论文
作者 | Cui ET(崔恩田)1; Wu YQ(吴玉琪); Wu YQ(吴玉琪)2; Zhang, Feng1; Xu, Ning3; Hou, Guihua1; Yu, Guiyun4; Ge, Chengyan4; Meng, Qiangqiang1 |
刊名 | Catalysis Communications |
出版日期 | 2018 |
卷号 | 103页码:29-33 |
ISSN号 | 1566-7367 |
关键词 | Photocatalysis Oxygen Vacancy Defect Level Band Mg4ta2o9-x Hydrogen Evolution |
DOI | 10.1016/j.catcom.2017.09.018 |
英文摘要 | Extending the light absorption range of wide-band-gap semiconductor oxides is crucial to the effective solar hydrogen energy conversion. Here, we introduced surface oxygen vacancies into Mg4Ta2O9 and constructed a narrow band-gap Mg4Ta2O9-x photocatalyst by a simple low temperature reduction method. The as-synthesized Mg4Ta2O9-x exhibits a significantly extended absorption edge in visible light range, which originates from the intermediate defect level band and electronic states created by introducing surface oxygen vacancy. With the same Pt loaded content (0.5 wt%), the Pt-loaded Mg4Ta2O9, exhibits the excellent photocatalytic stability and higher hydrogen evolution activity (4.42 μmol.h-1) than the Pt-loaded Mg4Ta2O9 (0.14 [μmol.h-1) under visible light irradiation. |
学科主题 | 物理化学与绿色催化 |
资助项目 | 环境催化与氢能研究组 |
语种 | 英语 |
WOS记录号 | WOS:000413887000007 |
资助机构 | the National Natural Science Foundation of China (NSFC) (No. 11404278;1164707;21603182;21703196);Jiangsu Province Research Joint Research Project (BY2016065-32) |
源URL | [http://210.77.64.217/handle/362003/22748] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Wu YQ(吴玉琪) |
作者单位 | 1.Yancheng Inst Technol, Key Lab Adv Technol Environm Protect Jiangsu Prov, Yancheng 224051, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 3.Yancheng Inst Technol, Phys Dept, Yancheng 224051, Peoples R China 4.Yancheng Inst Technol, Sch Chem & Chem Engn, Yancheng 224051, Peoples R China |
推荐引用方式 GB/T 7714 | Cui ET,Wu YQ,Wu YQ,et al. The roles of surface oxygen vacancy over Mg4Ta2O9-x photocatalyst in enhancing visible-light photocatalytic hydrogen evolution performance[J]. Catalysis Communications,2018,103:29-33. |
APA | Cui ET.,吴玉琪.,Wu YQ.,Zhang, Feng.,Xu, Ning.,...&Meng, Qiangqiang.(2018).The roles of surface oxygen vacancy over Mg4Ta2O9-x photocatalyst in enhancing visible-light photocatalytic hydrogen evolution performance.Catalysis Communications,103,29-33. |
MLA | Cui ET,et al."The roles of surface oxygen vacancy over Mg4Ta2O9-x photocatalyst in enhancing visible-light photocatalytic hydrogen evolution performance".Catalysis Communications 103(2018):29-33. |
入库方式: OAI收割
来源:兰州化学物理研究所
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