中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots

文献类型:期刊论文

作者Jiang, Xiao2; Xie, Erqing2; Wang, Fangcong2; Xie, Mingzheng1; Han, Weihua2,3; Li, Yunxia2; Mei, Junfeng2; Zhang, Zemin2
刊名Chemical Engineering Journal
出版日期2018
卷号331页码:48-53
ISSN号1385-8947
关键词Hydrogen Generation Bismuth Vanadate Quantum Effect Carbon Quantum Dot Charge Transfer Medium
DOI10.1016/j.cej.2017.08.102
英文摘要

Bismuth vanadate (BiVO4) has been widely studied as a promising candidate for oxygen evolution in artificial photosynthesis. However, it was seldom used in hydrogen generation because of its low conduction band and high reaction overpotential. Here, we proposed an effective strategy to address these issues by distributing BiVO4 quantum dots onto nanostructured tin oxide (SnO2). The nanostructured SnO2 simultaneously served as the host substrate and a passivation layer. Carbon quantum dots were also used to improve the charge transfer and electrocatalytic properties at the BiVO4-SnO2 interface. As expected, the final composite yields a net photo-current of 2.2 mA cm-2 at 0.6 V vs. Ag/AgCl, and a hydrogen generation rate of 0.54 μmol.h-1 without bias. The excellent performance was due to the enhanced electron energy, effective charge separation at the BiVO4-SnO2 interface, and the fast hole transfer from BiVO4 to carbon quantum dots and electrolyte.

学科主题材料科学与物理化学
语种英语
WOS记录号WOS:000414155500007
资助机构the National Natural Science Foundation of China (Grant Nos. U1531114;51572118;61404066);the Fundamental Research Funds for the Central University (China, Grant No. lzujbky-2017-180)
源URL[http://210.77.64.217/handle/362003/22767]  
专题兰州化学物理研究所_固体润滑国家重点实验室
通讯作者Xie, Erqing; Han, Weihua
作者单位1.College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China
2.School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China
3.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, China
推荐引用方式
GB/T 7714
Jiang, Xiao,Xie, Erqing,Wang, Fangcong,et al. Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots[J]. Chemical Engineering Journal,2018,331:48-53.
APA Jiang, Xiao.,Xie, Erqing.,Wang, Fangcong.,Xie, Mingzheng.,Han, Weihua.,...&Zhang, Zemin.(2018).Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots.Chemical Engineering Journal,331,48-53.
MLA Jiang, Xiao,et al."Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots".Chemical Engineering Journal 331(2018):48-53.

入库方式: OAI收割

来源:兰州化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。