Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots
文献类型:期刊论文
作者 | Jiang, Xiao2; Xie, Erqing2; Wang, Fangcong2; Xie, Mingzheng1; Han, Weihua2,3; Li, Yunxia2; Mei, Junfeng2; Zhang, Zemin2 |
刊名 | Chemical Engineering Journal
![]() |
出版日期 | 2018 |
卷号 | 331页码:48-53 |
关键词 | Hydrogen Generation Bismuth Vanadate Quantum Effect Carbon Quantum Dot Charge Transfer Medium |
ISSN号 | 1385-8947 |
DOI | 10.1016/j.cej.2017.08.102 |
英文摘要 | Bismuth vanadate (BiVO4) has been widely studied as a promising candidate for oxygen evolution in artificial photosynthesis. However, it was seldom used in hydrogen generation because of its low conduction band and high reaction overpotential. Here, we proposed an effective strategy to address these issues by distributing BiVO4 quantum dots onto nanostructured tin oxide (SnO2). The nanostructured SnO2 simultaneously served as the host substrate and a passivation layer. Carbon quantum dots were also used to improve the charge transfer and electrocatalytic properties at the BiVO4-SnO2 interface. As expected, the final composite yields a net photo-current of 2.2 mA cm-2 at 0.6 V vs. Ag/AgCl, and a hydrogen generation rate of 0.54 μmol.h-1 without bias. The excellent performance was due to the enhanced electron energy, effective charge separation at the BiVO4-SnO2 interface, and the fast hole transfer from BiVO4 to carbon quantum dots and electrolyte. |
学科主题 | 材料科学与物理化学 |
语种 | 英语 |
WOS记录号 | WOS:000414155500007 |
资助机构 | the National Natural Science Foundation of China (Grant Nos. U1531114;51572118;61404066);the Fundamental Research Funds for the Central University (China, Grant No. lzujbky-2017-180) |
源URL | [http://210.77.64.217/handle/362003/22767] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
通讯作者 | Xie, Erqing; Han, Weihua |
作者单位 | 1.College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China 2.School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China 3.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, China |
推荐引用方式 GB/T 7714 | Jiang, Xiao,Xie, Erqing,Wang, Fangcong,et al. Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots[J]. Chemical Engineering Journal,2018,331:48-53. |
APA | Jiang, Xiao.,Xie, Erqing.,Wang, Fangcong.,Xie, Mingzheng.,Han, Weihua.,...&Zhang, Zemin.(2018).Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots.Chemical Engineering Journal,331,48-53. |
MLA | Jiang, Xiao,et al."Improved photoelectrocatalytic hydrogen generation through BiVO4 quantum-dots loaded on nano-structured SnO2 and modified with carbon quantum-dots".Chemical Engineering Journal 331(2018):48-53. |
入库方式: OAI收割
来源:兰州化学物理研究所
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。