Advances in Manganese-Based Oxides Cathodic Electrocatalysts for Li-Air Batteries
文献类型:期刊论文
作者 | Liu B(刘宝)1,2,3; Sun YL(孙英伦)1; Liu, Li2,3; Xu S(许珊)2; Yan XB(阎兴斌)1; Xu S(许珊); Yan XB(阎兴斌) |
刊名 | Advanced Functional Materials |
出版日期 | 2018 |
卷号 | 28期号:15页码:1704973(1-34) |
ISSN号 | 1616-301X |
关键词 | Electrocatalytic Activity Li-air Batteries Manganese-based Oxides Oxygen Evolution Reactions Oxygen Reduction Reactions |
DOI | 10.1002/adfm.201704973 |
英文摘要 | Li–air batteries, characteristic of superhigh theoretical specific energy density, cost‐efficiency, and environment‐friendly merits, have aroused ever‐increasing attention. Nevertheless, relatively low Coulomb efficiency, severe potential hysteresis, and poor rate capability, which mainly result from sluggish oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) kinetics, as well as pitiful cycle stability caused by parasitic reactions, extremely limit their practical applications. Manganese (Mn)‐based oxides and their composites can exhibit high ORR and OER activities, reduce charge/discharge overpotential, and improve the cycling stability when used as cathodic catalyst materials. Herein, energy storage mechanisms for Li–air batteries are summarized, followed by a systematic overview of the progress of manganese‐based oxides (MnO2 with different crystal structures, MnO, MnOOH, Mn2O3, Mn3O4, MnOx, perovskite‐type and spinel‐type manganese oxides, etc.) cathodic materials for Li–air batteries in the recent years. The focus lies on the effects of crystal structure, design strategy, chemical composition, and microscopic physical parameters on ORR and OER activities of various Mn‐based oxides, and even the overall performance of Li–air batteries. Finally, a prospect of the research for Mn‐based oxides cathodic catalysts in the future is made, and some new insights for more reasonable design of Mn‐based oxides electrocatalysts with higher catalytic efficiency are provided. |
学科主题 | 材料科学与物理化学 |
资助项目 | 低维材料与化学储能课题组 ; 多相催化-2研究组 |
语种 | 英语 |
WOS记录号 | WOS:000430101100007 |
资助机构 | the National Nature Science Foundations of China (Grant Nos. 21573265 ; 21673263) |
源URL | [http://210.77.64.217/handle/362003/23656] |
专题 | 兰州化学物理研究所_清洁能源化学与材料实验室 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_固体润滑国家重点实验室 |
通讯作者 | Xu S(许珊); Yan XB(阎兴斌) |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lab Clean Energy Chem & Mat, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Inst Chem Phys, Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Liu B,Sun YL,Liu, Li,et al. Advances in Manganese-Based Oxides Cathodic Electrocatalysts for Li-Air Batteries[J]. Advanced Functional Materials,2018,28(15):1704973(1-34). |
APA | Liu B.,Sun YL.,Liu, Li.,Xu S.,Yan XB.,...&Yan XB.(2018).Advances in Manganese-Based Oxides Cathodic Electrocatalysts for Li-Air Batteries.Advanced Functional Materials,28(15),1704973(1-34). |
MLA | Liu B,et al."Advances in Manganese-Based Oxides Cathodic Electrocatalysts for Li-Air Batteries".Advanced Functional Materials 28.15(2018):1704973(1-34). |
入库方式: OAI收割
来源:兰州化学物理研究所
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