Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes
文献类型：期刊论文
| 作者 | Qin GP(秦贵平)1,3; Wang Y(王永)1; Huang HM(黄汉民)1,2; Huang HM(黄汉民)
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| 刊名 | Organic Letters
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| 出版日期 | 2017 |
| 卷号 | 19期号:23页码:6352-6355 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.7b03194 |
| 英文摘要 | Higher π-extended naphthalene, contained in methylnaphthalenes, which could capture alkyl radicals via SOMO–LUMO interactions, enabled the development of Cu-catalyzed formal [4 + 2] and [3 + 2] cycloadditions between methylnaphthalenes and electron-deficient alkenes. Under copper catalysis, a series of electron-deficient alkenes and methylnaphthalenes with different substituents were successfully incorporated with di-tert-butyl peroxide (TBP) as an oxidant and radical initiator, providing a wide range of cycloadducts. |
| 学科主题 | 物理化学与绿色催化 |
| 语种 | 英语 |
| WOS记录号 | WOS:000417229000023 |
| 资助机构 | the CAS Interdisciplinary Innovation Team ; the National Natural Science Foundation of China (21672199) |
| 源URL | [http://210.77.64.217/handle/362003/23782]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Huang HM(黄汉民) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin GP,Wang Y,Huang HM,et al. Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes[J]. Organic Letters,2017,19(23):6352-6355. |
| APA | Qin GP,Wang Y,Huang HM,&Huang HM.(2017).Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes.Organic Letters,19(23),6352-6355. |
| MLA | Qin GP,et al."Copper-Catalyzed Dehydrogenative Formal [4+2] and [3+2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes".Organic Letters 19.23(2017):6352-6355. |
入库方式： OAI收割
来源：兰州化学物理研究所
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