Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes
文献类型：期刊论文
| 作者 | Lv, Ji-Yuan1; Xu, Zheng1; Zheng ZJ(郑战江)1; Li, Li1; Cui, Yu-Ming1; Cao, Jian1; Yang KF(杨科芳)1; Xu LW(徐利文)1,2; Xu LW(徐利文) |
| 刊名 | RSC Advances
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:87页码:54934-54938 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c7ra11919d |
| 英文摘要 | The catalytic asymmetric copper-catalyzed conjugate addition of diethylzinc to α,β-unsaturated acylsilanes was found to proceed smoothly in moderate to good yields and promising enantioselectivities (up to 85% ee) in the presence of the multifunctional HZNU-Phos with both a phosphine center and BINOL-based diol moiety that played a crucial role in the achievement of the best enantioselectivity for this reaction. |
| 学科主题 | 物理化学与绿色催化 |
| 语种 | 英语 |
| WOS记录号 | WOS:000418378100002 |
| 资助机构 | the National Natural Science Foundation of China (No. 21472031;21703051;21773051);Zhejiang Provincial Natural Science Foundation of China (LZ18B020001;LY16E030009;LY17B030005;LY17E030003);Science and Technology Department of Zhejiang Province (2015C31138) |
| 源URL | [http://210.77.64.217/handle/362003/23789]  |
| 专题 | 兰州化学物理研究所_苏州研究院 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Li, Li; Xu LW(徐利文) |
| 作者单位 | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, 1378 Wenyi West Rd,Sci Pk HZNU, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Suzhou Res Insititue, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Ji-Yuan,Xu, Zheng,Zheng ZJ,et al. Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes[J]. RSC Advances,2017,7(87):54934-54938. |
| APA | Lv, Ji-Yuan.,Xu, Zheng.,Zheng ZJ.,Li, Li.,Cui, Yu-Ming.,...&徐利文.(2017).Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes.RSC Advances,7(87),54934-54938. |
| MLA | Lv, Ji-Yuan,et al."Enantioselective synthesis of chiral acylsilanes by copper/HZNU-Phos-catalyzed asymmetric conjugate addition of diethyzinc to α,β-unsaturated acylsilanes".RSC Advances 7.87(2017):54934-54938. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。