中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Totally Waterborne, Nonfluorinated, Mechanically Robust, and Self- Healing Superhydrophobic Coatings for Actual Anti-Icing

文献类型:期刊论文

作者Tian N(田宁)2,3; Zhao X(赵霞)1; Li YB(李亚斌)1,3; Li BC(李步成)3; Zhang JP(张俊平)3
刊名ACS Applied Materials& Interfaces
出版日期2018-10-23
卷号10期号:45页码:39391−39399
关键词Self-healing Silanes Superhydrophobic Surface Chemistry Waterborne
DOI10.1021/acsami.8b15061
英文摘要


Bioinspired superhydrophobic coatings are of great interest in academic and industrial areas. However, their real-world applications are hindered by some main bottlenecks, especially the pollutive preparation methods (e.g., organic solvents and fluorinated compounds) and poor mechanical stability. Here, we report for the first time the totally waterborne, nonfluorinated, mechanically robust, and self-healing superhydrophobic coatings. The coatings were fabricated by spray-coating polyurethane (PU) aqueous solution and a hexadecyl polysiloxane-modified SiO2(SiO2@HD-POS) aqueous suspension onto substrates using PU as the adhesive. The SiO2@HD-POS suspension was synthesized by HCl-catalyzed reactions among hexadecyltrimethoxysilane, tetraethoxysilane, and SiO2 nanoparticles. Besides high superhydrophobicity, the coatings exhibit exceptional mechanical stability against sandpaper abrasion for 200 cycles at 9.8 kPa and tape-peeling for 200 cycles at 90.5 kPa because of high durability and unique hierarchical macro-/nanostructure of the coating as well as solid lubrication of the SiO2@HD-POS nanoparticles fallen off from the coatings. The coatings also show fast and stable self-healing capability owing to migration of the healing agent (HD-POS) to the damaged surface. Moreover, the coatings exhibit good static and dynamic anti-icing performance in outdoor environment (-15 °C, relative humidity = 54%). The superhydrophobic coatings may be used in various areas because the main bottlenecks have been successfully broken.

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语种英语
源URL[http://210.77.64.217/handle/362003/24380]  
专题中国科学院兰州化学物理研究所
兰州化学物理研究所_环境材料与生态化学研究发展中心
兰州化学物理研究所_甘肃省黏土矿物应用重点实验室
通讯作者Zhang JP(张俊平)
作者单位1.兰州理工大学石油化工学院化学工程系
2.中国科学院大学
3.中国科学院兰州化学物理研究所,甘肃省黏土矿物应用重点实验室
推荐引用方式
GB/T 7714
Tian N,Zhao X,Li YB,et al. Totally Waterborne, Nonfluorinated, Mechanically Robust, and Self- Healing Superhydrophobic Coatings for Actual Anti-Icing[J]. ACS Applied Materials& Interfaces,2018,10(45):39391−39399.
APA Tian N,Zhao X,Li YB,Li BC,&Zhang JP.(2018).Totally Waterborne, Nonfluorinated, Mechanically Robust, and Self- Healing Superhydrophobic Coatings for Actual Anti-Icing.ACS Applied Materials& Interfaces,10(45),39391−39399.
MLA Tian N,et al."Totally Waterborne, Nonfluorinated, Mechanically Robust, and Self- Healing Superhydrophobic Coatings for Actual Anti-Icing".ACS Applied Materials& Interfaces 10.45(2018):39391−39399.

入库方式: OAI收割

来源:兰州化学物理研究所

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