Photodissociation of bromobenzene at 266 nm
文献类型：期刊论文
| 作者 | Zhang, H; Zhu, RS; Wang, GJ; Han, KL; He, GZ; Lou, NQ |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 1999-02-08 |
| 卷号 | 110期号:6页码:2922-2927 |
| 英文摘要 | the photodissociation of c6h5br at 266 nm has been investigated on the universal crossed molecular beam machine, and time-of-flight spectra as well as the angular distribution of br atom have been measured. photofragment translational energy distribution p(e-t) reveals that about 47% of the available energy is partitioned into translational energy. the anisotropy parameter beta at this wavelength is -0.7+/-0.2. from p(e-t) and beta, we deduce that c6h5br photodissociation is a fast process and the transition dipole moment is almost perpendicular to the c-br bond. ab initio calculations have been performed, and the calculated results show that the geometry of the first excited state of bromobenzene has changed apparently compared with that of the ground state. two kinds of possible fast dissociation mechanism have also been proposed. (c) 1999 american institute of physics. [s0021-9606(99)01206-4]. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | translational energy-distribution ; molecular-beams ; 193 nm ; angular-distribution ; excited-states ; aryl halides ; 248 nm ; photofragmentation ; fragment ; dissociation |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000078379800023 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/85273]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, H,Zhu, RS,Wang, GJ,et al. Photodissociation of bromobenzene at 266 nm[J]. journal of chemical physics,1999,110(6):2922-2927. |
| APA | Zhang, H,Zhu, RS,Wang, GJ,Han, KL,He, GZ,&Lou, NQ.(1999).Photodissociation of bromobenzene at 266 nm.journal of chemical physics,110(6),2922-2927. |
| MLA | Zhang, H,et al."Photodissociation of bromobenzene at 266 nm".journal of chemical physics 110.6(1999):2922-2927. |
入库方式： OAI收割
来源：大连化学物理研究所
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