中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane

文献类型:期刊论文

作者Li Gang; Chen Jie; Zhu Dao-Yong; Chen Ye; Xia Ji-Bao(夏纪宝); Xia Ji-Bao
刊名Adv. Synth. Catal
出版日期2018-05-02
期号360页码:2364 – 2369
关键词Carbon Dioxide Reduction Methylation Formylation Catalysis
DOI10.1002/adsc.201800140
英文摘要

We describe herein an efficient organocatalytic system for the selective N-methylation and Nformylation
of amines with carbon dioxide (CO2) as a sustainable C1 feedstock and polymethylhydrosiloxane
(PMHS) as a cost-effectvie reducing reagent. High-yielding N-methylation products are obtained with low
catalyst loading (1%) of DBU. Selective N-formylation of amines is achieved using the same catalytic system
at a lower reaction temperature

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语种英语
源URL[http://210.77.64.217/handle/362003/24725]  
专题中国科学院兰州化学物理研究所
通讯作者Chen Ye; Xia Ji-Bao(夏纪宝); Xia Ji-Bao
作者单位1.School Chemistry of Chemical Engineering, Guizhou University
2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou
3.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou
4.School Chemistry of Chemical Engineering, Guizhou University
5.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou
推荐引用方式
GB/T 7714
Li Gang,Chen Jie,Zhu Dao-Yong,et al. DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane[J]. Adv. Synth. Catal,2018(360):2364 – 2369.
APA Li Gang,Chen Jie,Zhu Dao-Yong,Chen Ye,Xia Ji-Bao,&Xia Ji-Bao.(2018).DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane.Adv. Synth. Catal(360),2364 – 2369.
MLA Li Gang,et al."DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane".Adv. Synth. Catal .360(2018):2364 – 2369.

入库方式: OAI收割

来源:兰州化学物理研究所

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