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Transition-Metal-Free Reductive Deoxygenative Olefination with CO2

文献类型：期刊论文

作者Zhu Dao-Yong; Li Wen-Duo; Yang Ce; Jie Chen; Xia Ji-Bao(夏纪宝）; Xia Ji-Bao
刊名Org. Lett.
出版日期2018-05-15
期号20页码:3282−3285
DOI10.1021/acs.orglett.8b01155
英文摘要

A new transition-metal-free reductive deoxygenative
olefination of phosphorus ylides with CO2, an abundant and
sustainable C1 chemical feedstock, is described. This catalytic CO2
fixation afforded β-unsubstituted acrylates and vinyl ketones in good
yields with broad scope and good functional group tolerance under
mild reaction conditions. Cost-effective and easily handled
polymethylhydrosiloxane was used as a reductant. Bis(silyl)acetal was proved to be the key intermediate in this reductive
functionalization of CO2

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语种英语
源URL[http://210.77.64.217/handle/362003/24728]  
专题中国科学院兰州化学物理研究所
通讯作者Xia Ji-Bao(夏纪宝）; Xia Ji-Bao
作者单位1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
3.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
4.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
5.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
推荐引用方式
GB/T 7714		 Zhu Dao-Yong,Li Wen-Duo,Yang Ce,et al. Transition-Metal-Free Reductive Deoxygenative Olefination with CO2[J]. Org. Lett.,2018(20):3282−3285.
APA Zhu Dao-Yong,Li Wen-Duo,Yang Ce,Jie Chen,Xia Ji-Bao,&Xia Ji-Bao.(2018).Transition-Metal-Free Reductive Deoxygenative Olefination with CO2.Org. Lett.(20),3282−3285.
MLA Zhu Dao-Yong,et al."Transition-Metal-Free Reductive Deoxygenative Olefination with CO2".Org. Lett. .20(2018):3282−3285.

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来源：兰州化学物理研究所

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