Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent
文献类型:期刊论文
作者 | Xu, F; Liang, XM; Lin, BC; Schramm, KW; Kettrup, A |
刊名 | journal of chromatography a
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出版日期 | 2002-08-30 |
卷号 | 968期号:1-2页码:7-16 |
关键词 | partition coefficients soil column chromatography retention factors hydrophobic organic compounds |
英文摘要 | the retention factors (k) of 104 hydrophobic organic chemicals (hocs) were measured in soil column chromatography (scc) over columns filled with three naturally occurring reference soils and eluted with milli-q water. a novel method for the estimation of soil organic partition coefficient (k-oc) was developed based on correlations with k in soil/water systems. strong log k-oc versus log k correlations (r>0.96) were found. the estimated k-oc values were in accordance with the literature values with a maximum deviation of less than 0.4 log units. all estimated k-oc values from three soils were consistent with each other. the scc approach is promising for fast screening of a large number of chemicals in their environmental applications. (c) 2002 elsevier science b.v. all rights reserved. |
WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
类目[WOS] | biochemical research methods ; chemistry, analytical |
研究领域[WOS] | biochemistry & molecular biology ; chemistry |
关键词[WOS] | phase liquid-chromatography ; adsorption-coefficient ; stationary phases ; s-triazine ; k-oc ; sorption ; chemicals ; herbicides ; desorption ; transport |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000177684800002 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/85467] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China 2.GSF, Natl Res Ctr Environm & Hlth, Inst Ecol Chem, D-85764 Neuherberg, Germany |
推荐引用方式 GB/T 7714 | Xu, F,Liang, XM,Lin, BC,et al. Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent[J]. journal of chromatography a,2002,968(1-2):7-16. |
APA | Xu, F,Liang, XM,Lin, BC,Schramm, KW,&Kettrup, A.(2002).Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent.journal of chromatography a,968(1-2),7-16. |
MLA | Xu, F,et al."Estimation of soil organic partition coefficients: from retention factors measured by soil column chromatography with water as eluent".journal of chromatography a 968.1-2(2002):7-16. |
入库方式: OAI收割
来源:大连化学物理研究所
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