Relationship between the molybdenum phases and the conversion of n-butane over Mo/HZSM-5
文献类型：期刊论文
| 作者 | Yuan, SD; Hamid, SBDA; Li, YX; Ying, PL; Xin, Q; Derouane, EG; Li, C |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2002-03-11 |
| 卷号 | 180期号:1-2页码:245-258 |
| 关键词 | n-C4H10 Mo/HZSM-5 molybdenum carbide MoO3 aromatization |
| 英文摘要 | the conversion of n-c4h10 was undertaken on moo3/hzsm-5 catalyst at 773-973k and the phases of molybdenum species were detected by xrd. the xrd results show that bulk moo3 on hzsm-5 can be readily reduced by n-c4h10 to moo2 at 773 k and moo2 can be gradually carburized to molybdenum carbide above 813 k. the molybdenum carbide formed from the carburization of moo2 with n-c4h10 below 893 k is alpha-moc1-x with fcc-structure, while hcp-molybdenum carbide formed above 933 k. during the evolution of moo3 to moo2 (>773 k) or the carburization of moo2 to molybdenum carbide (>813 k), deep oxidation, cracking and coke deposition are serious, in particular at higher reaction temperatures, these lead to the poor selectivity to aromatics. aromatization of n-c4h10 can proceed catalytically on both mo2c/hzsm-5 and moo2/hzsm-5, the distribution of the products for the two catalysts is similar below 813 k, but the, activity for mo2c/hzsm-5 is much higher than that for moo2/hzsm-5. (c) 2002 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | transition-metal carbides ; modified zsm-5 zeolites ; catalytic properties ; oxidative dehydrogenation ; surface-area ; aromatization ; isomerization ; nitrides ; platinum ; methane |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000174334600025 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/85673]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 3BX, Merseyside, England |
| 推荐引用方式 GB/T 7714 | Yuan, SD,Hamid, SBDA,Li, YX,et al. Relationship between the molybdenum phases and the conversion of n-butane over Mo/HZSM-5[J]. journal of molecular catalysis a-chemical,2002,180(1-2):245-258. |
| APA | Yuan, SD.,Hamid, SBDA.,Li, YX.,Ying, PL.,Xin, Q.,...&Li, C.(2002).Relationship between the molybdenum phases and the conversion of n-butane over Mo/HZSM-5.journal of molecular catalysis a-chemical,180(1-2),245-258. |
| MLA | Yuan, SD,et al."Relationship between the molybdenum phases and the conversion of n-butane over Mo/HZSM-5".journal of molecular catalysis a-chemical 180.1-2(2002):245-258. |
入库方式： OAI收割
来源：大连化学物理研究所
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