Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation
文献类型:期刊论文
作者 | Zhaorigetu, B; Li, WZ; Kieffer, R; Xu, HY |
刊名 | reaction kinetics and catalysis letters
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出版日期 | 2002 |
卷号 | 75期号:2页码:275-287 |
关键词 | propane oxidative dehydrogenation Ni-V-O catalysts synergetic effect |
英文摘要 | the oxidative dehydrogenation (odh) of propane was investigated on ni-v-o catalysts in a wide range of vanadium contents (5-40%). the addition of a small amount of vanadium significantly increased the catalytic activity of nio for oxidative dehydrogenation of propane to propene. the formation of propene has a good correlation with the coexistence of nio and ni3v2o8. this result strongly suggests that a synergetic effect exists between them in nixv1-xoy (x = 0.95 to 0.6). the best results were obtained with a high ni/v ratio (e.g. x = 0.95 to 0.85). the active sites and selective oxygen species are discussed. the influence of the catalyst preparation technique and the redox properties of the catalyst were also examined. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | mg-o catalysts ; oxide-based catalysts ; selective oxidation ; n-butane ; alkanes ; propene ; ethane ; redox |
收录类别 | SCI |
原文出处 | true |
语种 | 英语 |
WOS记录号 | WOS:000175136800010 |
公开日期 | 2010-11-30 |
源URL | [http://159.226.238.44/handle/321008/85765] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.LERCSI ECPM, F-67087 Strasbourg 2, France |
推荐引用方式 GB/T 7714 | Zhaorigetu, B,Li, WZ,Kieffer, R,et al. Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation[J]. reaction kinetics and catalysis letters,2002,75(2):275-287. |
APA | Zhaorigetu, B,Li, WZ,Kieffer, R,&Xu, HY.(2002).Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation.reaction kinetics and catalysis letters,75(2),275-287. |
MLA | Zhaorigetu, B,et al."Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation".reaction kinetics and catalysis letters 75.2(2002):275-287. |
入库方式: OAI收割
来源:大连化学物理研究所
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