中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation

文献类型:期刊论文

作者Zhaorigetu, B; Li, WZ; Kieffer, R; Xu, HY
刊名reaction kinetics and catalysis letters
出版日期2002
卷号75期号:2页码:275-287
关键词propane oxidative dehydrogenation Ni-V-O catalysts synergetic effect
英文摘要the oxidative dehydrogenation (odh) of propane was investigated on ni-v-o catalysts in a wide range of vanadium contents (5-40%). the addition of a small amount of vanadium significantly increased the catalytic activity of nio for oxidative dehydrogenation of propane to propene. the formation of propene has a good correlation with the coexistence of nio and ni3v2o8. this result strongly suggests that a synergetic effect exists between them in nixv1-xoy (x = 0.95 to 0.6). the best results were obtained with a high ni/v ratio (e.g. x = 0.95 to 0.85). the active sites and selective oxygen species are discussed. the influence of the catalyst preparation technique and the redox properties of the catalyst were also examined.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]mg-o catalysts ; oxide-based catalysts ; selective oxidation ; n-butane ; alkanes ; propene ; ethane ; redox
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000175136800010
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/85765]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.LERCSI ECPM, F-67087 Strasbourg 2, France
推荐引用方式
GB/T 7714
Zhaorigetu, B,Li, WZ,Kieffer, R,et al. Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation[J]. reaction kinetics and catalysis letters,2002,75(2):275-287.
APA Zhaorigetu, B,Li, WZ,Kieffer, R,&Xu, HY.(2002).Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation.reaction kinetics and catalysis letters,75(2),275-287.
MLA Zhaorigetu, B,et al."Synergetic effect between NiO and Ni3V2O8 in propane oxidative dehydrogenation".reaction kinetics and catalysis letters 75.2(2002):275-287.

入库方式: OAI收割

来源:大连化学物理研究所

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