Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters
文献类型：期刊论文
| 作者 | Wan, BS; Liao, SJ; Yu, DR |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 1999-07-05 |
| 卷号 | 183期号:1页码:81-84 |
| 关键词 | polymer-supported bimetallic catalyst synergic effect oxidative carbonylation carbamate esters |
| 英文摘要 | the polymer-supported bimetallic catalyst pvp-pdcl2-mncl2 (pvp=poly(n-vinyl-2-pyrrolidone)) exhibits high activity and selectivity for the oxidative carbonylation of amines with carbon monoxide and oxygen to carbamate esters under atmospheric pressure in the presence of a base (naoac). this catalyst is prepared by the addition of mncl2 to the alcoholic solution of pvp-pdcl2 in situ. a remarkable bimetallic synergic effect and the role of pvp in pvp-pdcl2-mxn (mxn=the second transition metal component such as nicl2, cocl2, mncl2 and fecl3) gives rise to an obvious increase in the conversion and selectivity for the reaction. among the second metal components tested, mn-pd exerts the strongest synergic effect. (c) 1999 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | homogeneous multimetallic catalysts ; carbon-monoxide ; mild conditions ; sodium hydride ; ruthenium ; hydroformylation ; hydrogenation ; olefins ; aniline ; halides |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000080489400008 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/86099]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wan, BS,Liao, SJ,Yu, DR. Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters[J]. applied catalysis a-general,1999,183(1):81-84. |
| APA | Wan, BS,Liao, SJ,&Yu, DR.(1999).Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters.applied catalysis a-general,183(1),81-84. |
| MLA | Wan, BS,et al."Polymer-supported palladium-manganese bimetallic catalyst for the oxidative carbonylation of amines to carbamate esters".applied catalysis a-general 183.1(1999):81-84. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。