A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds
文献类型：期刊论文
| 作者 | Jiang, H; Xu, Y; Liao, SJ; Yu, DR; Chen, H; Li, XJ |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 1999-06-10 |
| 卷号 | 142期号:2页码:147-152 |
| 关键词 | water-soluble bimetallic catalysts synergic effect hydrogenation aromatic nitrocompounds |
| 英文摘要 | hydrogenation of nitrobenzene can be catalyzed by the water-soluble catalyst pdcl2(tppts)(2) (tppts = tris(m-sulfonatophenyl)phosphine trisodium salt) under normal pressure at 65 degrees c in h2o/toluene biphasic solvent system. the exhibits higher catalytic activity and selectivity for the hydrogenation of aromatic nitrocompounds, compared with pdcl2(tppts)(2) or h2ptcl6 alone. the transmission electron micrographs demonstrate that the monometallic catalyst is composed of ultrafine palladium particles of almost uniform size while the particles of bimetallic catalyst are more widely distributed in size than those of the monometallic ones. (c) 1999 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | homogeneous multimetallic catalysts ; selective hydrogenation ; aqueous-solutions ; nitro-compounds ; ruthenium ; complexes ; clusters ; rhodium ; hydroformylation ; spectroscopy |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000079815100005 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/86135]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, H,Xu, Y,Liao, SJ,et al. A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds[J]. journal of molecular catalysis a-chemical,1999,142(2):147-152. |
| APA | Jiang, H,Xu, Y,Liao, SJ,Yu, DR,Chen, H,&Li, XJ.(1999).A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds.journal of molecular catalysis a-chemical,142(2),147-152. |
| MLA | Jiang, H,et al."A remarkable synergic effect of water-soluble bimetallic catalyst in the hydrogenation of aromatic nitrocompounds".journal of molecular catalysis a-chemical 142.2(1999):147-152. |
入库方式： OAI收割
来源：大连化学物理研究所
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